1stGen AHSS, AHSS, Press Hardened Steels, Steel Grades
Introduction
Press hardening steels are typically carbon-manganese-boron alloyed steels. They are also commonly known as:
- Press Hardening Steels (PHS)
- Hot Press Forming Steels (HPF), a term more common in Asia
- Boron Steel: although the name may also refer to other steels, in automotive industry boron steel is typically used for PHS
- Hot Formed Steel (HF), a term more common in Europe.
The most common PHS grade is PHS1500. In Europe, this grade is commonly referred to as 22MnB5 or 1.5528. As received, it has ferritic-pearlitic microstructure and a yield strength between 300-600 MPa depending on the cold working. The tensile strength of as received steel can be expected to be between 450 and 750 MPa. Total elongation must be over a minimum of 12% (A80), but depending on coating type and thickness may well exceed 18% (A80), see Figure 1*. Thus, the grade can be cold formed to relatively complex geometries using certain methods and coatings. When hardened, it has a minimum yield strength of 950 MPa and tensile strength typically around 1300-1650 MPa, Figure 1.B-14 Some companies describe them with their yield and tensile strength levels, such as PHS950Y1500T. It is also common in Europe to see this steel as PHS950Y1300T, and thus aiming for a minimum tensile strength of 1300 MPa after quenching.
The PHS1500 name may also be used for the Zn-coated 20MnB8 or air hardenable 22MnSiB9-5 grades. The former is known as “direct forming with pre-cooling steel” and could be abbreviated as CR1500T-PS, PHS1500PS, PHSPS950Y1300T or similar. The latter grade is known as “multi-step hot forming steel” and could be abbreviated as, CR1500T-MS, PHS1500MS, PHSMS950Y1300T or similar.V-9
Figure 1: Stress-Strain Curves of PHS1500 before and after quenching* (re-created after Citations U-9, O-8, B-18).
In the last decade, several steel makers introduced grades with higher carbon levels, leading to a tensile strength between 1800 MPa and 2000 MPa. Hydrogen induced cracking (HIC) and weldability limit applications of PHS1800, PHS1900 and PHS2000, with studies underway to develop practices which minimize or eliminate these limitations.
Lastly, there are higher energy absorbing, lower strength grades, which have improved ductility and bendability. These fall into two main groups: Press Quenched Steels (PQS) with approximate tensile strength levels of 450 MPa and 550 MPa (noted as PQS450 and PQS550 in Figure 2) and higher ductility PHS grades with approximate tensile strength levels of 1000 and 1200 MPa (shown as PHS1000 and PHS1200 in Figure 2).
Apart from these grades, other grades are suitable for press hardening. Several research groups and steel makers have offered special stainless-steel grades and recently developed Medium-Mn steels for hot stamping purposes. Also, one steel maker in Europe has developed a sandwich material by cladding PHS1500 with thin PQS450 layers on both sides.
Figure 2: Stress-strain curves of several PQS and PHS grades used in automotive industry, after hot stamping for full hardening* (re-created after Citations B-18, L-28, Z-7, Y-12, W-28, F-19, G-30).
PHS Grades with Tensile Strength Approximately 1500 MPa
Hot stamping as we know it today was developed in 1970s in Sweden. The most used steel since then has been 22MnB5 with slight modifications. 22MnB5 means, approximately 0.22 wt-% C, approximately (5/4) = 1.25% wt-% Mn, and B alloying.
The automotive use of this steel started in 1984 with door beams. Until 2001, the automotive use of hot stamped components was limited to door and bumper beams, made from uncoated 22MnB5, in the fully hardened condition. By the end of the 1990s, Type 1 aluminized coating was developed to address scale formation. Since then, 22MnB5 + AlSi coating has been used extensively.B-14
Although some steel makers claim 22MnB5 as a standard material, it is not listed in any international or regional (i.e., European, Asian, or American) standard. Only a similar 20MnB5 is listed in EN 10083-3.T-26, E-3 The acceptable range of chemical composition for 22MnB5 is given in Table 1.S-64, V-9
Table 1: Chemical composition limits for 22MnB5 (listed in wt.%).S-64, V-9
VDA239-500, a draft material recommendation from Verband Der Automotbilindustrie E.V. (VDA), is an attempt to further standardize hot stamping materials. The document has not been published as of early 2021. According to this draft standard, 22MnB5 may be delivered coated or uncoated, hot or cold rolled. Depending on these parameters, as-delivered mechanical properties may differ significantly. Steels for the indirect process, for example, has to have a higher elongation to ensure cold formability.V-9 Figure 1 shows generic stress-strain curves, which may vary significantly depending on the coating and selected press hardening process.
For 22MnB5 to reach its high strength after quenching, it must be austenitized first. During heating, ferrite begins to transform to austenite at “lower transformation temperature” known as Ac1. The temperature at which the ferrite-to-austenite transformation is complete is called “upper transformation temperature,” abbreviated as Ac3. Both Ac1 and Ac3 are dependent on the heating rate and the exact chemical composition of the alloy in question. The upper transformation temperature for 22MnB5 is approximately 835-890 °C.D-21, H-30Austenite transforms to other microstructures as the steel is cooled. The microstructures produced from this transformation depends on the cooling rate, as seen in the continuous-cooling-transformation (CCT) curve in Figure 3. Achieving the “fully hardened” condition in PHS grades requires an almost fully martensitic microstructure. Avoiding transformation to other phases requires cooling rates exceeding a minimum threshold, called the “critical cooling rate,” which for 22MnB5 is 27 °C/s. For energy absorbing applications, there are also tailored parts with “soft zones”. In these soft zones, areas of interest will be intentionally made with other microstructures to ensure higher energy absorption.B-14
Figure 3: Continuous Cooling Transformation (CCT) curve for 22MnB5 (Published in Citation B-19, re-created after Citations M-25, V-10).
Once the parts are hot stamped and quenched over the critical cooling rate, they typically have a yield strength of 950-1200 MPa and an ultimate tensile strength between 1300 and 1700 MPa. Their hardness level is typically between 470 and 510 HV, depending on the testing methods.B-14
Once automotive parts are stamped, they are then joined to the car body in body shop. The fully assembled body known as the Body-in-White (BIW) with doors and closures, is then moved to the paint shop. Once the car is coated and painted, the BIW passes through a furnace to cure the paint. The time and temperature for this operation is called the paint bake cycle. Although the temperature and duration may be different from plant to plant, it is typically close to 170 °C for 20 minutes. Most automotive body components made from cold or hot formed steels and some aluminum grades may experience an increase in their yield strength after paint baking.
In Figure 4, press hardened 22MnB5 is shown in the red curve. In this particular example, the proof strength was found to be approximately 1180 MPa. After processing through the standard 170 °C – 20 minutes bake hardening cycle, the proof strength increases to 1280 MPa (shown in the black curve).B-18 Most studies show a bake hardening increase of 100 MPa or more with press hardened 22MnB5 in industrial conditions.B-18, J-17, C-17
Figure 4: Bake hardening effect on press hardened 22MnB5. BH0 is shown since there is no cold deformation pre-strain. (re-created after Citation B-18).
There are two modified versions of the 22MnB5 recently offered by several steel makers: 20MnB8 and 22MnSiB9-5. Both grades have higher Mn and Si compared to 22MnB5, as shown in Table 2.
Table 2: Chemical compositions of PHS grades with 1500 MPa tensile strength (all listed in wt.%).V-9
Both of these relatively recent grades are designed for Zn-based coatings and are designed for different process routes. For these reasons, many existing hot stamping lines would require some modifications to accommodate these grades.
20MnB8 has been designed for a “direct process with pre-cooling”. The main idea is to solidify the Zn coating before forming, eliminating the possibility that liquid zine fills in the micro-cracks on the formed base metal surface, which in turn eliminates the risk of Liquid Metal Embrittlement (LME). The chemistry is modified such that the phase transformations occur later than 22MnB5. The critical cooling rate of 20MnB8 is approximately 10 °C/s. This allows the part to be transferred from the pre-cooling stage to the forming die. As press hardened, the material has approximately 1000-1050 MPa yield strength and 1500 MPa tensile strength. Once bake hardened (170 °C, 20 minutes), yield strength may exceed 1100 MPa.K-22 This steel may be referred to as PHS950Y1300T-PS (Press Hardening Steel with minimum 950 MPa yield, minimum 1300 MPa tensile strength, for Pre-cooled Stamping).
22MnSiB9-5 has been developed for a transfer press process, named as “multi-step”. As quenched, the material has similar mechanical properties with 22MnB5 (Figure 5). As of 2020, there is at least one automotive part mass produced with this technology and is applied to a compact car in Germany.G-27 Although the critical cooling rate is listed as 5 °C/s, even at a cooling rate of 1 °C/s, hardness over 450HV can be achieved, as shown in Figure 6.H-27 This allows the material to be “air-hardenable” and thus, can handle a transfer press operation (hence the name multi-step) in a servo press. This material is also available with Zn coating.B-15 This steel may be referred to as PHS950Y1300T-MS (Press Hardening Steel with minimum 950 MPa yield, minimum 1300 MPa tensile strength, for Multi-Step process).
Figure 5: Engineering stress-strain curves of 1500 MPa level grades (re-created after Citations B-18, G-29, K-22)
Figure 6: Critical cooling rates of 1500 MPa level press hardening steels (re-created after Citations K-22, H-31, H-27)
Grades with Higher Ductility
Press hardened parts are extremely strong, but cannot absorb much energy. Thus, they are mostly used where intrusion resistance is required. However, newer materials for hot stamping have been developed which have higher elongation (ductility) compared to the most common 22MnB5. These materials can be used in parts where energy absorption is required. These higher energy absorbing, lower strength grades fall into two groups, as shown in Figure 7. Those at the lower strength level are commonly referred to as “Press Quenched Steels” (PQS). The products having higher strength in Figure 7 are press hardening steels since they contain boron and do increase in strength from the quenching operation. The properties listed are after the hot stamping process.
- 450–600 MPa tensile strength level and >15% total elongation, listed as PQS450 and PQS550.
- 1000–1300 MPa tensile strength level and >5% total elongation, listed as PHS1000 and PHS1200.
Figure 7: Stress-strain curves of several PQS and PHS grades used in automotive industry, after hot stamping for full hardening* (re-created after Citations B-18, Y-12).
Currently none of these grades are standardized. Most steel producers have their own nomination and standard, as summarized in Table 3. There is a working document by German Association of Automotive Industry (Verband der Automobilindustrie, VDA), which only specifies one of the PQS grades. In the draft standard, VDA239-500, PQS450 is listed as CR500T-LA (Cold Rolled, 500 MPa Tensile strength, Low Alloyed). Similarly, PQS550 is listed as CR600T-LA.V-9 Some OEMs may prefer to name these grades with respect to their yield and tensile strength together, as listed in Table 3.
Table 3: Summary of Higher Ductility grades. The terminology descriptions are not standardized. Higher Ductility grade names are based on their properties and terminology is derived from a possible chemistry or OEM description. The properties listed here encompass those presented in multiple sources and may or may not be associated with any one specific commercial grade.Y-12, T-28, G-32
PQS grades have been under development at least since 2002. In the earliest studies, PQS 1200 was planned.R-11 Between 2007 and 2009, three new cars were introduced in Europe, having improved “energy absorbing” capacity in their hot stamped components. VW Tiguan (2007-2016) and Audi A5 Sportback (2009-2016) had soft zones in their B-pillars (Figure 8B and C). Intentionally reducing the cooling rate in these soft zone areas produces microstructures having higher elongations. In the Audi A4 (2008-2016) a total of three laser welded tailored blanks were hot stamped. The soft areas of the A4 B-pillars were made of HX340LAD+AS (HSLA steel, with AlSi coating, as delivered, min yield strength = 340 MPa, tensile strength = 410-510 MPa) as shown in Figure 8A. After the hot stamping process, HX340LAD likely had a tensile strength between 490 and 560 MPaS-65, H-32, B-20, D-22, putting it in the range of PQS450 (see Table 3). Note that there were not the only cars to have tailored hot stamped components during that time.
Figure 8: Earliest energy absorbing hot stamped B-pillars: (A) Audi A4 (2008-2016) had a laser welded tailored blank with HSLA material; (B) VW Tiguan (2007-2015) and (C) Audi A5 Sportback (2009-2016) had soft zones in their B-pillars (re-created after Citations H-32, B-20, D-22).
A 2012 studyK-25 showed that a laser welded tailored B-Pillar with 340 MPa yield strength HSLA and 22MnB5 had the best energy absorbing capacity in drop tower tests, compared to a tailored (part with a ductile soft-zone) or a monolithic part, Figure 9. As HSLA is not designed for hot stamping, most HSLA grades may have very high scatter in the final properties after hot stamping depending on the local cooling rate. Although the overall part may be cooled at an average 40 to 60 °C/s, at local spots the cooling rate may be over 80 °C/s. PQS grades are developed to have stable mechanical properties after a conventional hot stamping process, in which high local cooling rates may be possible.M-26, G-31, T-27
Figure 9: Energy absorbing capacity of B-pillars increase significantly with soft zones or laser welded tailored blank with ductile material (re-created after Citation K-25).
PQS grades have been in use at latest since 2014. One of the earliest cars to announce using PQS450 was VolvoXC90. There are six components (three right + three left), tailor welded blanks with PQS450, as shown Figure 10.L-29 Since then, many carmakers started to use PQS450 or PQS550 in their car bodies. These include:
- Fiat 500X: Patchwork supported, laser welded tailored rear side member with PQS450 in crush zonesD-23,
- Fiat Tipo (Hatchback and Station Wagon versions): similar rear side member with PQS450B-14,
- Renault Scenic 3: laser welded tailored B-pillar with PQS550 in the lower sectionF-19,
- Chrysler Pacifica: five-piece front door ring with PQS550 in the lower section of the B-Pillar areaT-29, and
- Chrysler Ram: six-piece front door ring with PQS550 in the lower section of the B-Pillar area.R-3
Figure 10: Use of laser welded tailored PQS-PHS grades in 2nd generation Volvo XC90 (re-created after Citation L-29).
Several car makers use PQS grades to facilitate joining of components. The B-Pillar of the Jaguar I-PACE electric SUV is made of PQS450, with a PHS1500 patch that is spot welded before hot stamping, creating the patchwork blank shown in Figure 11A.B-21 Early PQS applications involved a laser welded tailored blank with PHS 1500. Since 2014, Mercedes hot stamped PQS550 blanks not combined with PHS1500. Figure 11B shows such components on the Mercedes C-Class.K-26
Figure 11: Recent PQS applications: (a) 2018 Jaguar I-PACE uses a patchwork B-pillar with PQS450 master blank and PHS1500 patchB-21, (b) 2014 Mercedes C-Class has a number of PQS550 components that are not laser welded to PHS1500.K-26
PHS Grades over 1500 MPa
The most commonly used press hardening steels have 1500 MPa tensile strength, but are not the only optionsR-11, with 4 levels between 1700 and 2000 MPa tensile strength available or in development as shown in Figure 12. Hydrogen induced cracking (HIC) and weldability problems limit widespread use in automotive applications, with studies underway to develop practices which minimize or eliminate these limitations.
Figure 12: PHS grades over 1500 MPa tensile strength, compared with the common PHS1500 (re-created after Citations B-18, W-28, Z-7, L-30, L-28, B-14).
Mazda Motor Corporation was the first vehicle manufacturer to use higher strength boron steels, with the 2011 CX-5 using 1,800MPa tensile strength reinforcements in front and rear bumpers, Figure 13. According to Mazda, the new material saved 4.8 kg per vehicle. The chemistry of the steel is Nb modified 30MnB5.H-33, M-28 Figure 14 shows the comparison of bumper beams with PHS1500 and PHS1800. With the higher strength material, it was possible to save 12.5% weight with equal performance.H-33
Figure 13: Bumper beam reinforcements of Mazda CX-5 (SOP 2011) are the first automotive applications of higher strength boron steels.M-28
Figure 14: Performance comparison of bumper beams with PHS1500 and PHS1800.H-33
PHS 1800 is used in the 2022 Genesis Electrified G80 (G80EV) and the new G90, both from Hyundai Motor. A specialized method lowering the heating furnace temperature by more than 50℃ limits the penetration of hydrogen into the blanks, minimizing the risk of hydrogen embrittlement. L-64.
MBW 1900 is the commercial name for a press hardening steel with 1900 MPa tensile strength. An MBW 1900 B-pillar with correct properties can save 22% weight compared to DP 600 and yet may cost 9% less than the original Dual-Phase design.H-34 Ford had also demonstrated that by using MBW 1900 instead of PHS 1500, a further 15% weight could be saved.L-30 Since 2019, VW’s electric vehicle ID.3 has two seat crossbeams made of MBW 1900 steel, as seen in Figure 15.L-31 The components are part of MEB platform (Modularer E-Antriebs-Baukasten – modular electric-drive toolkit) and may be used in other VW Group EVs.
Figure 15: Underbody of VW ID3 (part of MEB platform).L-31
USIBOR 2000 is the commercial name given to a steel grade similar to 37MnB4 with an AlSi coating. Final properties are expected only after paint baking cycle, and the parts made with this grade may be brittle before paint bake.B-32 In June 2020, Chinese Great Wall Motors started using USIBOR 2000 in the Haval H6 SUV.V-12
HPF 2000, another commercial name, is used in a number of component-based examples, and also in the Renault EOLAB concept car.L-28, R-12 An 1800 MPa grade is under development.P-22 Docol PHS 1800, a commercial grade approximating 30MnB5, has been in production, with Docol PHS 2000 in development.S-66 PHS-Ultraform 2000, a commercial name for a Zn (GI) coated blank, is suited for the indirect process.V-11
General Motors China, together with several still mills across the country, have developed two new PHS grades: PHS 1700 (20MnCr) and PHS2000 (34MnBV). 20MnCr uses Cr alloying to improve hardenability and oxidation resistance. This grade can be hot formed without a coating. The furnace has to be conditioned with N2 gas. The final part has high corrosion resistance, approximately 9% total elongation (see Figure 12) and high bendability (see Table 4). 34MnBV on the other hand, has a thin AlSi coating (20g/m2 on each side). Compared with the typical thickness of AlSi coatings, thinner coatings are preferred for bendability (see Table 5).W-28 More information about these oxidation resistant PHS grades, as well as a 1200 MPa version intended for applications benefiting from enhanced crash energy absorption, can be found in Citation L-60.
Table 4: Chemical compositions of higher strength PHS grades. “0” means it is known that there is no alloying element, while “-” means there is no information. “~” is used for typical values; otherwise, minimum or maximum are given. The terminology descriptions are not standardized. PQS names are based on their properties and grade names are derived from a possible chemistry or OEM description. The properties listed here encompass those presented in multiple sources and may or may not be associated with any one specific commercial grade.W-28, B-32, H-33, G-33, L-28, S-67, S-66, Y-12, B-33
Table 5: Mechanical properties of higher strength PHS grades. “~” is used for typical values; otherwise, minimum or maximum are given. Superscript PB means after paint bake cycle. The terminology descriptions are not standardized. PQS names are based on their properties and grade names are derived from a possible chemistry or OEM description. The properties listed here encompass those presented in multiple sources and may or may not be associated with any one specific commercial grade.W-28, B-32, H-33, G-33, L-28, S-67, S-66, Y-12
Other Steels for Press Hardening Process
In recent years, many new steel grades are under evaluation for use with the press hardening process. Few, if any, have reached mass production, and are instead in the research and development phase. These grades include:
- Stainless steels
- Medium-Mn steels
- Composite steels
Stainless Steels
Studies of press hardening of stainless steels primarily focus on martensitic grades (i.e., AISI SS400 series).M-36, H-42, B-40, M-37, F-30 As seen in Figure 16, martensitic stainless steels may have higher formability at elevated temperatures, compared to PHS1500 (22MnB5). Other advantages of stainless steels are:
- better corrosion resistanceM-37,
- potentially higher heating rates (i.e., induction heating) F-30,
- possibility of air hardening – allowing the multi-step process — as seen in Figure 17a H-42,
- high cold formability – allowing indirect process – as seen in Figure 17b.M-37
Disadvantages include (a) higher material cost, and (b) higher furnace temperature (up to around 1050-1150 °C).M-37, F-30 As of 2020, there are two commercially available stainless steel grades specifically developed for press hardening process.
Figure 16: Tensile strength and total elongation variation with temperature of (a) PHS1500 = 22MnB5M-38 and (b) martensitic stainless steel.M-36
Figure 17: (a) Critical cooling rate comparison of 22MnB5 and AISI SS410 (re-created after Citation H-42), (b) Room temperature forming limit curve comparison of DP600 and modified AISI SS410 (re-created after Citation M-37).
Final mechanical properties of stainless steels after press hardening process are typically superior to 22MnB5, in terms of elongation and energy absorbing capacity. Figure 18 illustrates engineering stress-strain curves of the commercially available grades (1.6065 and 1.4064), and compares them with the 22MnB5 and a duplex stainless steel (Austenite + Martensite after press hardening). These grades may also have bake hardening effect, abbreviated as BH0, as there will be no cold deformation.B-40, M-37, F-30
Figure 18: Engineering Stress-Strain curves of press hardened stainless steels, compared with 22MnB5 (re-created after Citations B-40, M-37, F-30, B-41).
Table 6: Summary of mechanical properties of press hardenable stainless steel grades. Typical values are indicated with “~”. (Table generated from Citations B-40, M-37, F-30.)
Medium-Mn Steels
Medium-Mn steels typically contain 3 to 12 weight-% manganese alloying.D-27, H-30, S-80, R-16, K-35 Although these steels were originally designed for cold stamping applications, there are numerous studies related to using them in the press hardening process as well.H-30 Several advantages of medium-Mn steels in press hardening are:
- Austenitization temperature may be significantly lower than compared to 22MnB5, as indicated in Figure 19.H-30, S-80 Thus, using medium-Mn steels may save energy in heating process.M-39 Lower heating temperature may also help reducing the liquid-metal embrittlement risk of Zn-coated blanks. It also may reduce oxidation and decarburization of uncoated blanks.S-80
- Martensitic transformation can occur at low cooling rates. Simpler dies could be used with less or no cooling channels. In some grades, air hardening may be possible. Thus, multi-step process could be employed.S-80, B-14
- Some retained austenite may be present at the final part, which can enhance the elongation, through the TRIP effect. This, in turn, improves toughness significantly.S-80, B-14
Figure 19: Effect of Mn content on equilibrium transformation temperatures (re-created after Citations H-30, B-14)
The change in transformation temperatures with Mn-alloying was calculated using ThermoCalc software.H-30 As seen in Figure 19, as Mn alloying is increased, austenitization temperatures are lowered.H-30 For typical 22MnB5 stamping containing 1.1 to 1.5 % Mn, furnace temperature is typically set at 930 °C in mass production. The multi-step material 22MnSiB9-5 has slightly higher Mn levels (2.0 to 2.4 %), so the furnace temperature could be reduced to 890 °C. As also indicated in Table 7, the furnace temperature could be further lowered in hot forming of medium-Mn steels.
A study in the EU showed that if the maximum furnace temperature is 930 °C, which is common for 22MnB5, natural gas consumption will be around 32 m3/hr. In the study, two new medium-Mn steels were developed, one with 3 wt.% Mn and the other with 5 wt% Mn. These grades had lower austenitization temperature, and the maximum furnace set temperature could be reduced to 808 °C and 785 °C, respectively. Experimental data shows that at 808 °C natural gas consumption was reduced to 19 m3/hr, and at 785 °C to 17 m3/hr.M-39 In Figure 20, experimental data is plotted with a curve fit. Based on this model, it was estimated that by using 22MnSiB9-5, furnace gas consumption may be reduced by 15%.
Figure 20: Effect of maximum furnace set temperature (at the highest temperature furnace zone) on natural gas consumption (raw data from Citation M-39)
Lower heating temperature of medium-Mn steels may also help reducing the liquid-metal embrittlement risk of Zn-coated blanks. It also may reduce oxidation and decarburization of uncoated blanks.S-80
Medium-Mn steels may have high yield-point elongation (YPE), with reports of more than 5% after hot stamping. Mechanical properties may be sensitive to small changes in temperature profile. As seen in Figure 21, all studies with medium-Mn steel have a unique stress-strain curve after press hardening. This can be explained by:
- differences in the chemistry,
- thermomechanical history of the sheet prior to hot stamping,
- heating rate, heating temperature and soaking time, and
- cooling rate.S-80
Figure 21: Engineering Stress-Strain curves of several press hardened medium-Mn steels, compared with 22MnB5. See Table 7 for an explanation of each tested material (re-created after Citations S-80,L-37, W-30, L-38).
Table 7: Summary of mechanical properties of press hardenable Medium-Mn grades shown in Figure 18. Typical values are indicated with “~”. Toughness is calculated as the area under the engineering stress-strain curve. Items 4 and 5 also were annealed at different temperatures and therefore have different thermomechanical history. Note that these grades are not commercially available.L-38, W-30, L-37, S-80
Composite Steels
TriBond ® is the name given to a family of steel composites.T-32 Here, three slabs (one core material (60 to 80% of the thickness) and two cladding layers) are surface prepared, stacked on top of each other, and welded around the edges. The stack is hot rolled to thickness. Cold rolling could also be applied. Initially, TriBond ® was designed for wear-resistant cladding and ductile core materials.
The original design was optimized for hot stamping.B-14 The core material, where bending strains are lower than the outer layers, is made from generic 22MnB5 (PHS1500). Outer layers are made with PQS450. The stack is cold rolled, annealed and AlSi coated.Z-9 Two grades are developed, differing by the thickness distribution between the layers, as shown in Figure 22.R-14
Figure 22: Sample microsections of the conventional hot stamping grade PHS1500+AS, the high strength composite Tribond® 1400 and the high energy absorbing composite Tribond® 1200. The Tribond® 1200 microsection is experimental and is taken from Citation R-14. The other two images are renditions created by the author for explanation purposes. (re-created after Citations R-14, R-15)
Total elongation of the composite steel is not improved, compared to PHS1500, as shown in Figure 23. The main advantage of the composite steels is their higher bendability, as seen in Table 8. Crashboxes, front and rear rails, seat crossmembers and similar components experience axial crush loading in the event of a crash. In axial crush, Tribond® 1200 saved 15% weight compared to DP780 (CR440Y780T-DP). The bending loading mode effects B-pillars, bumper beams, rocker (sill) reinforcements, side impact door beams, and similar components during a crash. In this bending mode, Tribond® 1400 saved 8 to 10% weight compared to regular PHS1500. Lightweighting cost with Tribond® 1400 was calculated as €1.50/kgsaved.G-37, P-26
Figure 23: Engineering Stress-Strain curves of core layer, outer layer and the composite steel (re-created after Citation P-26).
Table 8: Summary of composite steels and comparison with conventional PHS and PQS grades. Typical values are indicated with “~”. (Table re-created after Citation B-14).
* Graphs in this article are for information purposes only. Production materials may have different curves. Consult the Certified Mill Test Report and/or characterize your current material with an appropriate test (such as a tensile, bending, hole expansion, or crash test) test to get the material data pertaining to your current stock.
For more information on Press Hardened Steels, see these pages:
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Forming, Press Hardened Steels
PHS and PQS Overview
A Brief Overview of Press Hardening
Press hardening (also commonly known as hot stamping or hot press forming) combines forming and heat treatment technology to create high strength complex shapes. Elevated temperature allows for production of complex shapes. This can be achieved by 10 different processes. To summarize:
- Forming from the “as delivered” ferritic-pearlitic microstructure (i.e., at ❶ in Figure 1). The formed part is later heated in a special furnace and quenched in a cooled press die. This process is commonly known as “Indirect Hot Stamping”, “Form Hardening” or “Post Form Heat Treatment”.
- Forming after heating a blank to over 880 °C to create an austenitic microstructure (i.e., at ❷ in Figure 1). The process is known as “Direct Hot Stamping”, “Press Hardening” or “Hot Press Forming”.
Selection of the process type usually depends on the coating and part complexity.
In press hardening, the required press forces are relatively low – compared to the final part strength – and springback is significantly reduced, if not eliminated. The parts get their final properties during the quenching cycle. In Press Hardening, OEMs require the final mechanical properties within the formed part to be guaranteed by the part supplier. In contrast, in cold stamping, the mechanical properties of the incoming sheet steel must be guaranteed by the steel supplier.
If the cooling rate is faster than the critical cooling rate of the steel, the final microstructure will be almost fully martensitic producing what is called the “Full Hard” (FH) condition. Depending on a part design, “soft zones” may be required. In this case, the heat treatment is controlled such that the soft zones have other phases such as bainite and in some cases ferrite and pearlite. The process of tailoring the microstructure distribution is called as “tailored tempering” or “tailored properties”. Parts with tailored properties may be described as a “multi-strength part” or a “tailored-part”.
Figure 1: A short summary of press hardening process (re-created after B-14).
Press hardening steels use carbon and manganese, with boron for additional hardenability. They have been used in the automotive industry since 1980s, however their use has increased significantly in the last two decades. There are mainly three groups of PHS grades:
- PHS1500 (see PHS Grades with TS approximately 1500 on link page): refers to the first and most commonly used PHS grade 22MnB5 or the recently developed grades like 20MnB8 used in the “pre-cooled direct process” or the air-hardening 22MnSiB9-5 used in the “multi-step process.” These grades have approximately 1,500 MPa (typical range: 1300-1650 MPa) tensile strength after quenching.
- Higher elongation grades – with some also known as Press Quenched Steels (PQS): PQS450, PQS550, PHS1000, and PHS1200 (see the section on Grades With Higher Ductility on the linked page): these grades have high elongation and/or bending angle after quenching. Tensile strength should range from 450 MPa to 1,300 MPa after the hot stamping process.
- Higher strength grades: PHS1800 and PHS2000 (see PHS Grades with TS over 1500 on link page): these grades have tensile strength of 1,800 MPa to 2,000 MPa after quenching.
- Emerging grades (see Other grades for press hardening process on link page for this and the stainless link following), such as Medium-Mn steels, and even some types of stainless steels are suitable for the hot stamping process.
Other PHS Pages in these Guidelines:
Press Hardened Steels – Metallurgy
PHS Production Methods
PHS Simulation
PHS Tailored Products
PHS Automotive Applications and Usage
Press Hardened Steels
Introduction
Some automotive components may require higher stiffness, strength, or energy absorbing capacity in a confined local area. One method to achieve these characteristics is to spot weld separate reinforcement panels to the main component. A strategy for improving energy absorption in high-strength components involves joining a second part made from a more ductile but lower strength material. Neither of these approaches are ideal in terms of manufacturing efficiency and product/process optimization.
Tailored parts are the term given to those parts that may have zones with different thickness, chemistry, or heat treatment, resulting in a reduced number of components, weight reduction, and/or lower costs. These goals are achieved through part consolidation and by reducing or in some cases even eliminating joining operations.
In cold stamping operations, tailored parts (tailored products) are typically produced at the incoming coil or blank level, but are typically called “tailored blanks” or the specific process/product produced:
- Laser Welded Tailored Blanks (LWTB, also known as Tailor Welded Blanks, or TWB) or Tailor Welded Coils (TWC – not common in press hardening),
- Tailor Rolled Blanks (TRB) or Tailor Rolled Coils (TRC),
- Tailor Welded Tubes (TWT) or Tailor Rolled Tubes (TRT), or
- Patchwork Blanks,
In press hardened components, a single component may be press hardened such that it has what are known as soft zones, or areas of lower hardness possessing increased ductility. The tailored processing of these multi-strength parts can be achieved byB-14:
- Controlling the incoming blank temperature, (Tailored Heating, pre-process)
- Controlling the quenching rate, (Tailored Quenching, during process)
- Partially tempering (Tailored Tempering, post-process).
These are typically called tailored parts or tailor processed parts. Lastly it is also possible to combine two techniques, that is, making a tailored part using a tailored blank.
Laser Welded Tailored Blanks (Tailor Welded Blanks)
Laser Welded Tailored Blanks (LWTB) are blanks that are produced by laser butt welding of two or more sub-blanks, as shown in Figure 1. In the industry, the terms Tailor Welded Blanks (TWB) and Laser Welded Blanks (LWB) are also used interchangably.M-46
Figure 1: Steps of making a press hardened laser welded tailored blank (re-created after Citations B-14 and A-8).
Laser welded tailored blanks consist of sub-blanks with:
- Different thicknesses, allowing for use of thinner sheet steels in areas of the component having less rigorous loading requirements. Using thinner sheets saves weight.
- Different grades, optimizing the energy absorption and intrusion resistance characteristics in each area of the same part (such as an automotive B-pillar, see Figure 6b).
- A combination of both.
Laser welded tailored blanks with the same thickness and grade are used to create blanks having dimensions larger than mill rolling or processing capabilities.
Laser welded tailored blanks offer many paths to weight savings and cost reduction, including:
- Reducing the number of parts in the subassembly, such as the need for reinforcements;
- Reducing the number of required forming tools, welding fixtures, etc.; and
- Improved raw material utilization by sub-blank nesting optimization (see Figure 1 and Figure 10c).
The weld area of press hardened laser welded blanks may not transform to martensite, and therefore may show a significant reduction in the hardness. This can be attributed to weld quality and quenching rate.B-47, W-3
Blanked edge geometry of the sub-blanks (notches, underfillings and weld seam pollution) affects weld quality. Separating the blanking into two operations, rough blanking and precision blanking, may improve blanked edge geometry and the resulting weld quality.M-46
As seen in Figure 1, Aluminium-Silicon (AS) coated sub-blanks may require a secondary ablation operation. The AS coating is removed (ablated) near the weld edge, typically by using a laser. When this AS coating is not removed and filler wire is not used, the aluminium from the coating may pollute the weld. When welding two PHS1500 sub-blanks together, an aluminium-polluted weld may have significantly lower hardness, as shown in Figure 2. A part made of such a blank will fail at the weld zone, both in quasi-static and dynamic conditions.E-8
Figure 2: Effect of ablation and filler wire on hardness distribution around the laser weld of equal thickness PHS1500+AS150 (re-created after Citation E-8).
Another common type of laser welded tailored blank is where a press hardening steel (typically PHS1500) is welded to a press quenched steel (PQS 450 or 550). Lower strength and higher ductility should be observed in the PQS. Without ablation, a hardness drop is observed in AS coated welded blank, seen in Figure 3a. In quasi-static tests, fracture was observed in the PQS base metal. In dynamic tests, the part failed at the weld zone. When ablation is applied, a B-pillar with a PQS base absorbs more energy compared to the welded blank without ablation.E-8 In uncoated and Zn-coated steels, ablation is not required since there is no concern about aluminium pollution in the weld.A-68, M-2 Figure 3b shows the hardness distribution in the weld seam of galvanized sub-blanks.
Figure 3: Hardness distribution in PHS-PQS laser welded blanks. a) AS coated sub-blanks with and without ablation (re-created after Citation E-8); b) Galvanized sub-blanks without ablation (re-created after Citation M-2). Note that the initial thicknesses of sub-blanks are different.
There are two methods of ablation. Full ablation removes the AS coating and the interdiffusion layer (IDL) in their entirety. In contrast, partial ablation removes only the AS coating, but the IDL remains intact. Full ablation may result in oxidation and decarburization in the weld seam.E-8, W-3
In addition to weld pollution, the hardness drop in the weld seam could also be caused by the local quenching rate. When a welded blank is made using sub-blanks with different thicknesses, misalignment (Δx in Figure 4a) may lower the quenching rate. Misalignment greater than 2 mm could cause over 30% hardness drop, from approximately 500 HV to less than 350 HV.B-47 A filler wire with high-C content could reduce the critical cooling rate, as shown in the Figure 4b. In a particular example using a filler wire containing 0.3% C presented in this image, the critical cooling rate was reduced to approximately 13 °C/s. Due to the high-C content, a 20% increase in the weld seam hardness may be possible,E-8 as indicated in Figure 2.
Figure 4: a) Misalignment of the blank in the die could cause lower quenching rate in the weld seam (re-created after Citation B-47); b) A high-carbon filler wire may reduce the critical cooling rate (re-created after Citation E-8).
The fourth generation Audi A4 (2008-2016 also known as B8) contained some of the earliest applications of press hardened laser welded tailored blanks. The car had five components made of blanks with tailored properties: tunnel reinforcement, left/right B-pillar reinforcements, and left/right rear rails, as shown in Figure 5. As PQS grades were not commercially available at that time, High-Strength Low-Alloy (HSLA) steels were used for energy absorbing applications. As delivered, HX340LAD + AS, had a minimum 340 MPa yield strength. Press hardened parts and their final mechanical properties are shown in Figure 5.S-65
Figure 5: PHS applications in Audi A4 (2008-2016). The car had a total of three different components and five parts using laser welded tailored blanks (figure and table re-created using data and images from Citations S-65, D-11, V-21, W-5, and S-13).
In Citation K-25, using a laser welded tailored blank resulted in the highest energy absorbing capacity of a B-pillar reinforcement. In this study, PHS1500 (22MnB5) was laser welded to a HC340LA (uncoated HSLA steel with minimum 340 MPa incoming yield strength). Such a welded blank could absorb 3.3 kJ energy without fracture, whereas a monolithic (same thickness, same hardness all around) PHS1500 failed at 2.3 kJ (see Figure 6). PHS1500 with soft zones (see the Tailored Properties section below) passed a 2.3 kJ test but failed at 3.3 kJ.
Figure 6: Energy absorbing capacity of B-pillars increase significantly with soft zones or laser-welded ductile material (re-created after Citation K-25).
Conventional High-Strength Steels are not designed for hot stamping process. HSLA 340 and 410 MPa grades (minimum yield strength, as delivered) and CMn440 steel (Carbon-manganese alloyed, minimum 440 MPa tensile strength at delivery) may be softer than their as-delivered condition when heated over austenitization temperature and slowly cooled at 15 °C/s cooling rate. Furthermore, if the local cooling rate is over 60 to 80 °C/s, a significant increase in hardness (see Figure 7) and sharp decrease in elongation may be observed.D-22, T-27
Figure 7: Vickers hardness variation of several cold stamping steels after austenitization and at different cooling rates (re-created using data from Citation D-22).
Development of PQS grades started around 2007, targeting consistent mechanical properties over a wide range of cooling rates. Currently, typical laser welded blank applications of PQS450 and PQS550 in the automotive industry include B-pillars, front rails, and rear rails. One such car with LWTB components is the 2nd generation Volvo XC90 (2014-Present). The car has a total of 152 kg hot stamped parts, with approximately 132 kg of PHS1500 and 20 kg PQS450, comprising 33% and 5% of the BIW (excluding doors and closures), respectively. The XC90 has a total of six hot stamped welded blanks (three left and three right), as seen in Figure 8.L-29, L-8 More details about welded blanks with PQS450 and PQS550 are presented in the Grades with Higher Ductility Section within our article on PQS Grades.
Figure 8: Use of laser welded PQS-PHS grades in the 2nd generation Volvo XC90 (re-created after Citation L-29).
Recently PHS1000 and PHS1200 grades have been developed. The yield and tensile strength of these grades increase with hot stamping, and as such are considered press hardening steels. Y-12, G-30 More details about these grades are presented in the Grades with Higher Ductility Section within our article on PQS Grades. Renault conducted an experimental study in 2021 to replace PHS1500-PQS550 laser welded tailored blanks with those made from a PHS2000-PHS1000 combination. As seen in Figure 9, the new materials can absorb the same amount of energy with less intrusion. At the same level of intrusion, the energy absorbing capacity improves by 30%.B-62
Figure 9: Stroke vs. energy curves of representative sub-assemblies, emulating B-pillar (re-created after Citation B-62).
Laser welded tailored blanks may also be used to create larger blanks that may not be otherwise possible or economically feasible.M-4 Door rings represent one such application for hot stamping, as introduced by ArcelorMittal in 2010.A-17 A prototype door ring was produced in 2012, using four sub-blanks, including one PQS550, as shown Figure 10a. The part measured approximately 1500 mm long and 1250 mm high.B-63, T-1 May 2013 saw the first application of a hot stamped door ring with the introduction of the 3rd generation Acura MDX, running from 2013-2020. The vehicle used a two sub-blank LWB door ring, both PHS1500, with thicknesses of 1.2 mm and 1.6 mm. Through sub-blank nesting optimization, material utilization was improved to 63%. Details can be seen in Figures 10b and 10c.M-46
Figure 10: Door rings. a) one of the earliest concepts from 2010T-1; b) the first mass produced door ring of the 2013 Acura MDX; c) sub-blank nesting to improve the material utilization.M-46
For door ring manufacturing, a higher tonnage press with larger bolster area may be required, as well as a wider furnace and heavier capacity transfer systems. In most hot stamping lines, typically two or four parts are formed and quenched in one stroke (known as 2-out or 4-out) to improve productivity and reduce the total cost per piece. Due to the large size and additional requirements, door ring manufacturing is typically 1-out. However, as the part itself replaces four components (A and B pillars, hinge pillar and rocker reinforcement), it can be as cost effective as a 4-out hot stamping operation.W-6
Although not common, the Acura TLX (1st generation 2015-2021) and Hyundai Santa Fe (since 2018, 4th generation) utilize single piece (not from a welded blank) door rings with 1.4 mm and 1.1 mm thicknesses respectively. B-14, H-4 The 2nd generation Acura TLX (2021-present) has the door-ring of the 1st generation model as a carryover.L-61
Since its inception, laser welded door rings have been used in several Honda / Acura models. The number of sub-blanks was increased to 4 with the 2nd generation Honda Ridgeline (2017-present). This was the first door ring application in a pick-up truck.B-52 The Chrysler Pacifica started production in 2017 with 5 sub-blanks, as shown in Figure 11a, including PQS550 for crash energy absorption.T-19 The 5th generation RAM 1500 pick-up truck, which debuted in 2018, has a six sub-blank door ring, as seen in Figure 11b.R-3 In 2018, Acura RDX became the first car to have inner and outer door rings made of PHS1500 laser welded blanks. As seen in Figures 11c and 11d, five and four sub-blanks were used respectively for the inner and outer door rings, all PHS1500. This design further allowed downgauging and lightweighting.R-26
Figure 11: Laser welded door ring applications: (a) Chrysler Pacifica (SOP 2017) has five sub-blanks (recreated after Citation T-19); (b) RAM 1500 (SOP 2018) has six sub-blanks (re-created after Citation R-3); Acura RDX was the first car to have two door rings: (c) inner and (d) outer, both with four sub-blanks of PHS1500 (re-created after R-26).
Currently, the European Standard for Laser Welded Tailored Blanks (LWTB), EN 10359D-2, covers only LWTBs for cold stamping materials. This standard will be expanded to include press hardened laser welded blanks, with an expected release in 2023.
Tailor Rolled Blanks
Tailor Rolled Blanks (TRB) or variable thickness rolled blanks (VTRB) are produced by a secondary cold rolling of an already cold rolled and possibly coated coil. In this secondary cold rolling, the roll gap is adjusted during the process so that the thickness can be varied (tailored) locally, shown in the left image of Figure 12. TRBs can be an alternative to “same material-different thickness” welded blanks.B-14 Contrary to an LWB, thickness changes are not abrupt, but instead are continuous. Thus, TRBs do not have stress concentration due to the notch effect. Problems associated with weld quality in welded blanks (pollution, geometry, quenching rate, etc.) do not apply to TRBs since welding the blank is not necessary.H-7
Tailor rolled blanks are typically named by their thicknesses from head-to-tail, and symmetrical sections with same thicknesses are written once. For example, the B-pillars of previous generation Ford Focus (2011-2018), as shown in the right image of Figure 12, has five thicknesses in nine zones. This blank would be named as: 1.35-2.30-2.10-2.40-2.70. The process starts with a 2.70 mm thick coil, and thickness reductions up to 50% would be completed during the tailor rolling process. The typical slope in the Thickness Transition Zones (TTZ) are 1:100, meaning 1 mm change in thickness would require a 100 mm long TTZ. Different slopes could also be utilized.Q-7, H-8
Figure 12: Left image: Principle of tailor rolling process (re-created after Citation Z-5); Right image: thickness profile and nesting of a B-pillar in a tailor rolled coil (re-created after Citation Q-7).
The tailor rolling process squeezes and thins any coating, and possibly damages the coating as well.T-4 For this reason, TRBs are typically used in dry areas. Because of similar reasons, in AS coated TRB applications, AS150 (75 g/m2 on each side, Al-Si coating) is preferred instead of thinner coatings such as AS80.
One of the first press hardened TRB applications was the B-pillar reinforcement of the BMW X5 (2nd generation, 2006-2013). The application saved 4 kg/car, compared to a monolithic press hardened part.P-1 Other applications include: heel piece of MQB (Modularer Querbaukasten, translating from German to “Modular Transversal Toolkit) platform cars – covering many VW Group cars with transverse engine orientation, since 2012S-107, front crossmember of MLB Evo (Modularer Längsbaukasten, translating from German to “Modular Longitudinal Matrix) platform cars – covering Audi vehicles with longitudinal engine orientation, since 2015H-44, and roof crossmember of the 10th generation Honda Accord (2017-present).M-7 Many other OEMs use tailor rolled blanks, with a more detailed list presented in Citation B-14.
Figure 13: Several TRB applications in recent vehicles (re-created after Citations H-44, P-1, S-107, and M-7).
Patchwork Blanks
In a patchwork blank, one or more “patch blanks” (reinforcements) are overlapped with a “master blank” and spot welded. The spot-welded blanks are then heated in a furnace and hot stamped as a single piece in one stroke. The final part will have increased thickness in the areas of interest. A patchwork blank may reduce the need for post-forming assemblies of reinforcements, as seen in Figure 14. Since the spot welds are also austenitized and quenched, their hardness distribution is typically better than spot welding after hot stamping, as shown clearly in Figure 15.B-20, U-12, N-3
Figure 14: Master blank and patch geometries of a sample B-pillar: (a) before, and (b) after spot welding, (c) after hot stamping (re-created after Citations B-14 and L-52).
Figure 15: Hardness distribution in a spot weld, comparing when spot welding is done before or after press hardening, (Re-created after Citations B-14 and U-12)
Patchwork blanks allow for the possibility of reducing the number of forming tools and the associated fixed costs. Stamping and post-process joining costs may be reduced as well, leading to a variable cost reduction. Depending on how the part is engineered, a weight savings may be achieved. These benefits come at the expense of the additional blanking operation to create the patch blanks, and the pre-process welding stations.U-12, T-42
Optimizing the initial geometry of the patch blank helps reduce these costs. One approach is to use a one-step inverse simulation in the early planning / feasibility phase. In this method, the initial outline is estimated based on deformation theory of plasticity, requiring only relatively short CPU-times (in the order of a few minutes using a modern PC), with low accuracy (up to 3 mm deviation is common). A trim optimization method is recommended during the design phase of the patch blank blanking dies. In this method, an incremental solver is used with an initially assumed blank outline. Typically, the result of one-step solution is used for the first iteration. The software then compares the outline of the patch after forming and calculates the differences with the desired geometry. Then the initial geometry is modified accordingly, and another forming simulation is carried out. These iterations continue until the deviation is less than the set tolerances. For example, in a B-pillar patch optimization, ±0.25 mm deviation may be achieved in two to three iterations.W-8, Z-12, S-108
Reducing the number of spot welds also reduces the cost of the patch blank. Minimizing the number of spot welds may also reduce the cycle time in welding stations. In some cases, it may also affect the number of spot-welding stations — thus, the initial fixed cost. However, severe wrinkles may form if using an insufficient number of spot welds. Using finite element analysis may assist in finding the optimum number of spot welds for formability.A-19 In some cases, although the part could be hot formed with a smaller number of spot welds without any problems, more spot welds are applied for crash performance.U-12
Some of the earliest patchwork PHS applications were used in the B-pillars of 3rd generation Volvo V70 (2007-2016) and Fiat 500 (2007-present). In the Volvo V70, a total of 46 spot welds were used to create the patchwork blank. Both blanks were uncoated PHS1500, with a 1.4 mm thick master blank and a 2.0 mm thick patch.L-53 In the Fiat 500, the master blank was 2 mm thick, supported by a 1 mm thick patch, both AS coated, as seen in Figure 16a.Z-13 In recent years, patchwork PHS blanks have been used in more car bodies, including but not limited to several parts in the 2nd generation Volvo XC90 (2014-Present)L-29, rear rail of the Fiat 500X (2014-Present)M-45, B-pillar of the Opel Astra K (2015-Present)K-8, B-pillar of the 2nd generation Range Rover EvoqueF-1, and several Subaru models.U-12, A-73
In the rear rail of the Fiat 500X, the master blank is laser welded with 1.5 mm PHS1500 and 1.6 mm PQS450 sub-blanks. The patch blank is a 1.5 mm thick PHS1500.M-45 A similar design with different thicknesses was also used in Fiat Tipo/Egea, as shown in Figure 16b.B-14 For the Opel Astra, the master blank is a 1.3 mm thick PHS1500 with soft zones (see the Tailored Properties discussion below). The patch is a TRB with 1.00-1.95-1.00 thickness distribution.K-8
Figure 16: Sample automotive applications of patchwork PHS: B-pillar reinforcements of (a) 2007 Volvo V70 (re-crated after Citation N-4), (b) 2007 Fiat 500 (re-created after Citation Z-13); and (c) rear rail of 2015 Fiat Tipo/Egea (Citation T-43, recreated after Citation B-14).
Jaguar I-PACE is an aluminium-intensive electric SUV making its debut in 2018. In this car, the B-pillar reinforcement is made up of a patchwork blank. Contrary to most earlier applications, the master blank is a PQS450, which could be joined easily to the rest of the body by mechanical joining. The patch is PHS1500, which improves the side impact and roof crush performance.B-21 In 2018, a global Tier 1 supplier showed the possibility of using PHS2000 master blank and patch for a rear bumper beam.N-6
Improvements in patchwork blank technology includes the weld type and quality. Conventional resistance spot welding has been used in making patchwork blanks. There are studies on using remote laser welding for this purpose as well. In one study, joining a patchwork blank with approximately 50 welds was completed in 35 seconds using 2.2 kW laser power, and in 23 seconds using 2.8 kW.L-54 Another study showed that when laser welding is used with AS-coated blanks, weld strength is reduced by approximately 40% compared to uncoated blanks.G-1
“Overlap patch blanks” are a sub-set of patchwork blanks. As seen in Figure 17a, instead of a master and patch blanks, two (or more) sub-blanks are spot welded over an “overlap region” to create a blank like a laser welded tailored blank. The technology was initially applied in cold stamped components.P-4 Recently an international tier 1 supplier developed door rings and floor panels made from overlap patch blanks that were press hardened. As seen in Figure 17 b and c, a door ring can be created using 5 sub-blanks, including one PQS (shown in green).G-3
Figure 17: Overlap patch blanks: (a) schematic of a B-pillar blank (re-created after B-75), (b) door ring concept from outer view, and (c) inner view.G-3
One of the benefits of using overlap patch blanks is the ability to build up larger welded blanks of Al-Si coated steel without the need to employ ablation technology. The overlapped sub-blanks can be resistance spot welded together, thereby avoiding the risk of aluminum polluting the weld pool that ablation would otherwise mitigate.
Patches can be engineered to increase stiffness in critical locations, and the spot welds provide easy adjustment to both the blank and weld as needed.
Figure 18: Overlap patch blanks created with resistance spot welding eliminates the need to use laser welding and ablation techniques.S-111
Tailored Properties
Tailored properties is a term used for the technology to make a part with hard and soft zones. Hard zones are nearly 100% martensitic, whereas soft zones have a lower percentage of martensite. This type of part may be called a “multi-strength part”. In Europe, the term “tailored tempering” may be used to denote a part with tailored properties. In this article, tailored tempering describes a part which was press hardened as a whole and later locally softened to modify properties in specific areas.
Soft zones may be used for several reasons:
- To improve crashworthiness: Local areas with higher ductility aid in crash energy absorption. An example B-pillar is shown in Figure 6. This type of usage is very common in B-pillars, front rails, and rear rails, as shown in Figure 8. The first application for this purpose was realized in the B-pillar of the first-generation VW Tiguan (2007-2018).S-13 The technology is also used in rear rails. Both applications are shown in Figure 19. The technology is also used in rear rails of 10th generation Honda Civic (2015-present)C-22, and 10th generation Honda Accord (2017-present). In this particular application, shown in Figure 20, soft zones were designed such that the rear frame would deform in a pre-defined manner and absorb the crash energy efficiently.C-22, M-7, K-52 Tailored parts are used for improved energy absorption in numerous models from Audi, BMW, Ford, Honda, Mercedes and others.B-14
Figure 19: Rear rail assembly of Honda Civic (10th gen., 2015-Present): (a) Isometric view of the assembly, (b) bottom view of the frame, during rear crash condition (re-created after Citation K-52). A similar design was also employed in Honda Accord.M-7
Figure 20: Example uses of soft zones for improved energy absorption: (a) first application was in 1st generation (2007-2018) VW Tiguan’s B-pillars (re-created after Citations V-22 and M-8), (b) a more recent application in 2013 Ford Escape’s rear rails (known as Ford Kuga in EU, sold between 2013 and 2019) (re-created after Citation M-59).
- To improve weld/joint strength: When base metal hardness is over 350 HV, the heat affected zone (HAZ) in the spot weld may be the weakest point of an assembly.B-20 Several other studies have proven the hardness drop and early fractures around spot weld of fully hardened parts, as summarized in Figure 21. When flanges are induction tempered (see the Tailored Tempering discussion below, a B-pillar assembly may absorb 30% more energy than a fully hardened B-pillar.H-61, F-2 In multi-material mix cars, such as the 2nd generation Audi Q7 (2015-present), “soft flanges” can be used for mechanical joining the PHS B-pillar reinforcement to aluminium components. Hemming of aluminium, around the PHS, can also be used to join the components.H-62
Figure 21: When spot welding is done on a soft zone: (a) hardness distribution would not have a soft HAZ, and (b) early fractures at spot welds are not observed (re-created after Citations B-14, H-61, and B-64).
- For secondary bending operations: Tailored tempering (softening areas of interest after a fully hardened press hardening process) may be used in bumper beams, where a secondary bending may be required to form an inner flange.L-40
- To facilitate trimming/piercing: Although not very common, local soft zones may reduce the force/energy requirements and improve the cutting tool life if hard trimming will be used.L-55
There are three methods to create the soft zones leading to tailored properties:B-14
- Tailored heating during austenitization of the blank (typically achieved in the furnace),
- Tailored quenching after austenitization (can be achieved in tempering stations or in the forming die),
- Tailored tempering after fully hardening a part (after the press hardening process).
1) Tailored Heating (Pre-Process)
In tailored heating, areas of interest (the soft zones) are not fully austenitized. The critical heating temperature has been reported as 750 °C by several researchers. When heated below 750 °C and hot stamped, the part has a tensile strength of approximately 600 MPa and over 15% total elongation. As seen in Figure 22, mechanical properties will stay relatively constant with heating temperatures between 650 and 750 °C. Above this critical heating temperature, hardness (almost directly proportional with tensile strength) may increase significantly.K-53
Figure 22: Effect of blank heating temperature on hardness and converted tensile strength of PHS1500 (re-created after Citation K-53).
There are several methods to achieve tailored heating. In the direct process, where an undeformed blank is being heated, there were four main methods proposed:
- Using a divided furnace,
- Masking soft zones in furnace,
- Heating by segmented contact plates, and
- Conduction heating with controlled current flow.
A divided roller hearth furnace may have gas or electric heating for the first half of its length, ensuring a uniform temperature distribution during heating. In the second half of the furnace length (soaking zone), there may be several electric heating zones across the furnace width direction that can be set to different temperatures. To simplify the schematic, Figure 23 shows a two-zone divided furnace. In the soaking zone, five-zone furnaces were already available as early as 2011. By 2018, furnaces with 32 zones were industrially used to make parts for several German OEMs.H-47, E-12, O-13
Figure 23: Divided furnace concept (simplified with two zones): (a) temperature setting in the furnace affects the temperature distribution in the soft and hard zones; (b) in the tailored soaking area, up to 32 zones may be realized (re-created after Citations B-14, E-12, and O-13).
As heating of the blank in furnace is mostly achieved by radiation, an insulating mask may reduce the local temperature in the soft zones. Ceramic insulators or machined steel blocks may be used for masking purposes. Areas that are not masked will be heated above the austenitization temperature, whereas the masked areas will be at lower temperatures.N-3 Figure 24 shows a schematic of the process. In addition to masking duty, the inlay should have enough heat capacity to absorb the heat from the blank. When steel inlays (masks) are used, they should be thicker than the blank to have the necessary heat capacity. Stainless steels could be used to avoid scaling of the steel inlay.B-65, B-66
Figure 24: (a) Using masking for tailored heating (re-created after Citations B-14 and N-3); (b) an example mask and blank from Citation K-54.
Although not commonly used for mass production, it was proven that contact plates may be used in tailored heating. Blanks are isolated from the environment during contact plate heating, significantly reducing oxidation on uncoated blanks. Fraunhofer IWU in Chemnitz, Germany, has developed a lab-scale contact plate heater that can generate soft zones. In the hard zones (those heated over 900 °C), the heating rate may be as high as 300 °C/s. The heater and a sample blank are shown in Figure 25.S-109, G-48
Figure 25: Tailored heating in contact plate heating: (a) right after the heating before the discharge, (b) a tailor heated blank with dimensions and approximate temperatures (re-created after Citation S-109).
Two different strategies were developed to generate tailored heat blanks using conductive heating while ensuring no current passes through the targeted soft zones.M-60 These approaches are applicable only to rectangular blanks. Researchers in Hanover University improved the technology to heat non-rectangular blanks with tailored temperature distribution. In a sample (non-rectangular) B-pillar blank, temperature was kept at 950 °C in the heated zones and approximately at 700 °C in the soft zones. Significant temperature drops were observed in the proximity of electrodes, resulting in non-uniform heating.B-67 Neither of the techniques are used in mass production for tailored parts.
In the indirect hot stamping process, the parts are formed prior to heating. Thus, it is not practical to apply any of the earlier strategies to get a cold zone in the part. For such components, soft zones are generated by using machined steel blocks known as absorption masses, which have high heat capacity to absorb the heat from the blank. As seen in Figure 26, correctly sized absorption masses keep the soft zones below 750 °C. When quenched, these areas have approximately 500 MPa tensile strength, over 20% total elongation (A50) and over 150° bending angle according to VDA bending test. The tailored parts have narrow transition zones, and are spot weldable, both in hard and soft zones. The technology is used in the B-pillar reinforcements of several BMW models.M-2, K-53, R-27
Figure 26: Tailored heating of galvanized PHS1500 in the indirect process: (a) Blank temperature evolution in hard and soft zones, in a roller hearth furnace using absorption mass in the soft zone; (b) hardness distribution and approximate tensile strength in hard and soft zones (re-created after Citation K-53).
Tailored heating technologies are beneficial for their energy efficiency, as the soft zones are heated to lower temperatures. The technology may be applied to uncoated and Zn-coated blanks; however, AS-coated blanks are at risk for incomplete coating diffusion in the soft zones. For these reasons, similar technologies (excluding conduction heating) also are used in a secondary heating device after the furnace.O-13 These techniques are listed in the Intermediate Pre-Cooling section below.
2) Tailored Quenching
In tailored quenching methods, the whole blank is austenitized in the furnace and the cooling rate is controlled such that the soft zones cannot develop high percentages of martensite. This can be achieved by two main process routes:
- Intermediate pre-cooling, where a secondary furnace is employed where the temperature of hard zones is maintained, but soft zones are allowed to cool.
- In-die cooling, where a fully austenitized blank with uniform temperature distribution is placed on the tool, but the part is cooled at different cooling rates through several process routes.
Intermediate Pre-Cooling
Complete coating diffusion does not occur in AS-coated blanks subjected to tailored heating profiles. To ensure the full coating diffusion and uniformity of the coating all around the blank, the blanks must be fully austenitized. One of the earliest approaches kept the hard zones in the roller hearth furnace, while extending the soft zones out of the furnace. This technology produced a part with two zones only, with a linear transition zone (Figure 27). AS-coating is fully developed for weldability and e-coat adhesion. Tailored properties are reproducible. For this furnace-extending method, no extra investment is necessary other than automation programming.L-56
Figure 27: Simplest pre-cooling technology: extending the soft zones out of the furnace. (a) Schematic of extending out of furnace (not to scale, from Citation B-55), (b) B-pillars made by this technology.A-74
Intermediate pre-cooling can also be done in a divided furnace. In this case, contrary to Figure 23a, the uniform heating temperature is set over 885 °C. The soft zone area is then set to a lower temperature and thus pre-cooled. The rear rails of the 2013 Ford Escape shown in Figure 20b are produced with this technique.M-59
Most of the tailored heating strategies discussed so far are suitable only for larger soft zone areas, but not for small areas. Intermediate pre-cooling by extending out of furnace and pre-cooling using a divided furnace strategy can only produce a two-zone tailored part, such as in Figure 28b. Since 2011, there has been an interest in producing three-zone tailored parts. By 2015, the Audi Q7 employed a three zone B-pillar with soft flanges for joining purposes. Soft spot weld areas are also under development.H-62, A-74, B-68
Figure 28: Tailored B-pillar evolution: (a) monolithic, (b) two-zones tailored, (c) three-zones tailored, (d) soft flanges, (e) soft spots (re-created after Citations A-74, B-68, P-3).
To address these challenges, several intermediate cooling systems have been developed. AP&T uses multi-layer furnaces, with an addition of a TemperBox®. The blanks are austenitized in the multi-layer furnace. Before being fed into the press, the blanks are first moved into another layer (the TemperBox®) where re-heating is done with masking. Masked areas cool below 700 °C, whereas the unmasked areas are re-heated to 930 °C. The cycle time varies between 30 and 70 seconds, depending on the thickness of the blanks (Figure 29). For continuous production, one TemperBox® supports five-chamber furnaces.K-41
Figure 29: Time-temperature evolution in the TemperBox®.K-41
Similar technologies have been developed by other furnace makers: Schwartz has developed a thermal printer which can be a stand-alone unit or installed at the end of a roller hearth furnace.L-56 EBNER has developed their PACC module, which can be integrated to a roller hearth furnace and cools the areas of interest by contact cooling.O-13
In-Die Tailored Cooling
In this process, the blanks are fully austenitized in the furnace, but the cooling rate is locally adjusted. Areas with a local cooling rate over 27 °C/s are expected to transform to nearly 100% martensite. In soft zones, cooling rates should be lower than this critical number. The cooling rate is a function of the thermal contact conductance (see Figure 31a) and the temperature gradient (ΔT) between the tool surface and the blank. Thus, lower cooling rates can be achieved byB-14, M-61:
- Heated die inserts,
- Die relief method, or
- Local die inserts with low thermal conductivity.
If a segment of the die is heated, sections of the blank in contact with this area have a smaller temperature gradient (ΔT), leading to reduced heat flow and lower cooling rates. In addition, sometimes this phenomenon occurs unintentionally if the dies are not cooled efficiently and hot spots are observed.B-14
In the automotive industry, heated die inserts are used typically between 300 °C and 550 °C. Typically electric cartridge heaters are used, Figure 30a. If the inserts are heated over 420 °C (the martensite start temperature for 22MnB5), no martensite formation occurs while the blank is in contact with the dies. For productivity purposes, sheets should stay in the dies as short as possible. After industrial quenching times (10-15 seconds), soft zones may still have phase transformation during air cooling in the exit conveyor. This may cause distortion in the final part. One simulation study found that 80 seconds of air cooling was needed to transform all the austenite into other phases.B-14, M-61, B-69, B-70
Figure 30: Tailored parts with heated die inserts: (a) Simulation model with cooling channels in hard zones and heating in soft zones, (b) phase transformation may continue in soft zones.B-70
This process has been applied as early as 2009 (if not earlier) in the Audi A5 Sportback.B-20 The car had a three-zone B-pillar, similar to the sketch in Figure 28c. Since then, several complicated geometries have been realized in an industrial scale with “heated die insert” technology. In 2015, the 10th generation Honda Civic was equipped with complicated rear rails, shown in Figure 19. These components are also made with heated inserts.C-22 Also debuting in 2015, the Audi Q7 was equipped with B-pillar reinforcements with soft band and soft flanges (similar to Figure 28d).H-62 As of 2021, heated dies appear to be one of the most common process routes to create tailored parts.
Another method to get lower cooling rates is to reduce the contact pressure or introduce an air gap between the blank and the die. As seen in Figure 31a, as the contact is lost, thermal contact conductance (hc, the amount of heat passing through the unit area of blank to the tool) is reduced significantly. For example, at 5 MPa contact pressure, hc is equal to 1.5 kW/m2°K. As soon as the contact is lost, the value is less than 0.3 kW/m2°K.B-70 A Schematic showing an “air gap” design for soft flanges is presented in Figure 31c and compared with a conventional die in Figure 31b.C-4
Figure 31: (a) Thermal contact conductance is less than 0.3 kW/m2°K, once there is an air gap (own work, raw data from Citations O-14 and M-62); (b) schematic of a conventional press hardening die, (c) introducing air gap to obtain soft flanges.C-4
Use of insulated die inserts is another method to obtain tailored cooling. These reduce the heat flow from the blank to the die. Typical hot forming tool steels have a heat conductivity of 27-32 W/m2°K. When ceramic insulators with less than 6 W/m2°K conductivity are used (Figure 32a), the inserts will heat over 200 °C after a few strokes. In the meantime, tool steel temperature is around 60 °C, as they can dissipate more heat energy. The strength in the soft zones may be as low as 650 MPa, corresponding to approximately 200 HV hardness.K-55 The method may not be feasible for mass production, as the first few parts will not have the same strength/elongation level until a “steady-state” is achieved, shown in Figure 32b and 32c. In real production conditions, the production may be halted for maintenance, safety, or work hours reasons.
Figure 32: Insulating inserts: (a) experimental die set at TU Graz, (b) hardness distribution of the first part, (c) hardness distribution after a few cycles (re-created after Citations B-14 and K-55).
3) Tailored Tempering (Post-Process Annealing)
The last method for obtaining tailored properties is to produce soft zones by annealing a fully hardened part. This can be done by induction or laser, as seen in Figure 32. Post-process annealing is relatively simple to implement, as the blank is heated and quenched uniformly in press hardening line. Annealing is added as a follow-up operation, which adds cost, but gives flexibility. The number of soft zones, their geometries and mechanical properties can be varied during the project timeline. Soft zones could be adjusted for different cars/variants that share the same component but require different soft zones.B-14, G-48, J-22
With this approach, however, final properties of soft zones may vary significantly depending on the temperature-time curves. Several studies have shown yield strength may spread from 450 MPa to 1300 MPa, and tensile strength between 550 and 1350 MPa. In addition, geometric distortion may also occur, since the heating and cooling is done in a local area. Finally, surface and coating conditions may change, affecting weldability, corrosion resistance and/or e-coat adhesion.L-40, M-61, B-72
BMW has been using induction annealed B-pillars in their 3-Series Sedan/Touring (2011-2019) and X5 SUV (2013-2018)R-27, and possibly other vehicles. Volvo has studied the technology with induction annealing, Figure 33a.H-61 Benteler has been using induction annealing for secondary bending of bumper beams.L-40 Gestamp evaluated laser tempering on prototype parts, Figure 33b.B-71
Figure 33: Post-process tailored annealing can be done by: (a) inductionH-61, and/or (b) laser.B-71
Post Hardening Processing: Trimming
Options include setting the trim line with a developed blank, laser cutting, soft zones, hard trimming, and hot cutting.
A developed blank might be appropriate for areas which can accommodate larger tolerances.
Soft zone development to aid in easier trimming and joining is discussed in the prior section.
Laser trimming leads to improved fatigue strength and raises the failure strains, but suffers from relatively long cycle times, high capital investment and maintenance cost. More powerful high-end lasers measurably reduce cycle times.
Hard trimming is not usually the best long-term option for high volume applications since the hardness of the PHS part is about the same as the hardness of trim steels. A harder, more wear resistant tool steel would now fail by chipping.
Hard trimming creates burrs, large shear zone, and microcracks in the fracture zone. Each of these lowers the fracture strain required for failure, which lowers component crashworthiness.
Trimming of fully hardened PHS needs extra consideration since the scale formed on uncoated PHS leads to abrasive wear and Al-Si coatings may stick to the tool creating galling conditions. A PVD coating improves wear resistance. World-class operations which use hard trimming specify advanced powder metallurgy tool steels with advanced tool coatings.
In-die hot cutting may occur after heating but before forming, and is usually limited to approximately 90° cuts. Microstructural changes occurring during the heating and cooling cycle influences flange position tolerances.
Hot cutting may also occur after forming but before quenching. This approach requires less force and causes reduced damage to the tooling and dies since the steel is softer to cut. One challenge is that the formed part is cooling during the cutting operation, with the part changing dimensions as it cools. Hot cutting improves cycle time and may reduce capital investment. Grains of fine ferrite rather than martensite form at hot sheared edge, reducing the delayed fracture risk associated with hydrogen embrittlement.
Honda developed this process to both trim the part as well as create holes during hot stamping to replace time- and energy-intensive laser cutting. (Figure 33, Figure 34). Their approach uses a high-speed hydraulic system, and further reduces cooling time by spraying the part with water. The first production application was the 2012 Honda N-Box Center Pillar Reinforcement. H-49, S-112
Figure 33: Honda N-Box Center Pillar Reinforcement created with In-Die Trimming during Hot Stamping. H-49
Figure 34: Internal Die Trimming Process at Honda.H-49
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Press Hardened Steels
In its simplest explanation hot stamping consists of five operations: (1) blanking (or cutting-to-length), (2) forming, (3) heating, (4) cooling (quenching) and (5) trimming/piercing. Each process route listed below has a distinct order or type of these operations.
In most sources, hot stamping is explained with only two processes: Direct hot stamping (also known as Press Hardening) and indirect hot stamping (also known as Form Hardening). While this used to be accurate, there are currently at least 10 processes for part manufacturing:
- Direct Process (Blanking > Heating > Forming > Quenching > Trimming)
- Indirect Process (Blanking > Forming & Trimming > Heating > Quenching > Trimming)
- Hybrid Process (Blanking > 1st Forming > Heating > 2nd Forming > Quenching > Trimming)
- Pre-cooled Direct Process (Blanking > Heating > Pre-cooling > Forming > Quenching > Trimming)
- Multi-Step Process (Blanking > Heating > Pre-cooling > Forming and Trimming > Air Quenching)
- Form Fixture Hardening (Roll Forming > Cut-to-length > Heating > Bending forming > Quenching > Trimming / piercing)
- Roll Form PHS (Roll Forming > Heating > Quenching > Cut-to-length > Trimming & piercing)
- Form Blow Hardening / Hot gas metal forming (Cut-to-length tube or roll formed / welded profile > Heating > Pressure forming > Quenching > Piercing)
- 3DQ (Cut-to-length tube > Local induction heating > 3-D Bending > Direct Water Quenching > Piercing)
- STAF (Cut-to-length tube > Cold preforming > Heating > Pressure Forming > Quenching > Piercing)
The video below explains some of these processes and how they are employed at Gestamp Automoción. Here, Paul Belanger, Director of Gestamp’s North American R&D Center, was interviewed by Kate Bachman, the Editor of STAMPING Journal®. Thanks are given to Paul and Kate, as well as FMA, Fabricators & Manufacturers Association®, for permission to reproduce this video.
Direct Process
The most common process route in hot stamping is still the direct process (also known as press hardening).D-20 Here, previously cut blanks are heated typically in a roller hearth or a multi-chamber furnace to over 900 °C to create a fully austenitic microstructure. Depending on the material handling system, transfer from the furnace to the press may take up 6 to 10 seconds.B-14 During this time, the blank may cool down to 700 °C.G-24 Forming is done immediately after the blanks are transferred on the die, and should be completed before the blank cools below 420 °C.G-24, K-18 The blanks are formed in hot condition (state ❷ in Figure 1), and quenched in the same die to achieve the required properties. For 22MnB5 steel, if the quenching rate is over 27 °C/s, the part will transform to almost 100% martensite. For productivity purposes, higher cooling rates are often realized.K-18 Typical cycle times for a direct process with the 22MnB5 chemistry could be between 10 and 20 seconds, depending on the thickness.B-14 Global R&D efforts target improvements in cycle time.
The process is typically used for bare/uncoated steels or AlSi coated steels. Zn coated blanks are not suitable for direct process, as pure Zn melts around 420 °C and GA (Zn-Fe) coatings around 530-780 °C. (see Figure 3)G-25 If forming is done with liquid Zn over the blank, microcracks may fill with Zn and lower the fatigue strength of the final part significantly.K-20 A recently developed alloy minimizes these concerns, as explained in the “Pre-cooled Direct Process” section below.
Figure 1: Summary of hot stamping processes. In direct process forming is done at state ❶, in indirect process at ❷B-14
Typical Al-Si coatings prevent scale formation and decarburization at elevated temperatures. The aluminum-rich coating contains 7% to 11 wt.% Si, and acts as a barrier to offer corrosion resistance during service.F-14 In automotive industry, typical coating weights are AS150 (75 g/m2 coating on each side) or AS80 (40 g/m2 coating on each side).A-51 Refer to our page on Al-Si coatings for more details.
When using uncoated blanks, controlled atmosphere in the furnace helps avoid excessive decarburization and scale formation. Surface scale locally changes the critical cooling rate, alters the metal flow and friction, and leads to premature tool wear. Without a controlled atmosphere, a surface conditioning step like shot blasting may be required after forming to remove the scale.A-52 Varnish coatings may also be used with direct hot stamping.
Formed parts must be trimmed and pierced to final geometry. In the direct process, the most common trimming method is laser cutting. The capital expense and cycle times associated with laser trimming factor into overall part cost calculations. In most plants, for every hot stamping line, there are 3 to 5 laser trimming machines.B-14
The grades used with the direct process may be referred to as PHS950Y1500T-DS (Press Hardening Steel with minimum 950 MPa yield, minimum 1500 MPa tensile strength, for Direct [Hot] Stamping).
Indirect Process
(Blanking > Forming & Trimming > Heating > Quenching > Surface Conditioning)
Typically used for galvanized blanks, indirect hot stamping, also known as form hardening, starts by cold forming the part (at ❶ in Figure 1) in a transfer press or a tandem transfer line. The direct process is limited in that only one forming die can be used. However, the indirect process can accommodate multiple die stations, allowing for the production of more complicated geometries, even those with undercuts. The part has almost the final shape exiting the cold forming press, where piercings and trimming could also be completed. The formed parts are then heated in a special furnace and quenched in a second die set.B-14,K-21,F-15
BMW 7 Series (2008-2015, codenamed F01) was the first car to have Zn-coated indirect hot stamped steel in its body-in-white.P-20 Zn-based coatings are favored for their cathodic protection. Zn-coated blanks may develop a thin oxide layer during heating, even if a protective atmosphere is used in the furnace. This layer helps preventing evaporation of the Zn (pure Zn evaporates at 907 °C at 1 atm. pressure), but must be removed before welding and painting. To achieve this, sandblasting, shot blasting or dry-ice (CO2) blasting are typically used.F-14, F-15 The grades for indirect process may be referred to as PHS950Y1500T-IS (Press Hardening Steel with minimum 950 MPa yield, minimum 1500 MPa tensile strength, for Indirect [Hot] Stamping).
The indirect process cannot be applied to Al-Si coated blanks, as they have a hard but brittle intermetallic layer which would crack during cold deformation.F-14
Hybrid (2-Step) Process
(Blanking > 1st Forming > Heating > 2nd Forming > Quenching > Trimming > Surface Conditioning)
In this process, as summarized in Figure 2, some of the forming occurs at the cold stage [❶ in Figure 1]. The semi-formed part then is heated in the furnace, significantly deformed to a final shape [❷ in Figure 1] and subsequently quenched in the same die. This process had found greater use in Europe, especially for deep drawn parts such as transmission tunnels. To avoid scale formation in the furnace and hot forming, a special varnish-type coating is commonly used. The final part must be surface cleaned with a process like shot blasting before welding to remove the varnish coating.S-63 Since the early 2010s, the process has been replaced by the direct process of Al-Si-coated blanks.N-15
Figure 2: Summary of “hybrid process” where deformation is done both at cold and hot conditions.B-14
Pre-Cooled Direct Process
(Blanking > Heating > Pre-cooling > Forming > Quenching > Trimming > Surface conditioning)
A galvannealed (GA) coating primarily contains zinc and iron, and solidifies at temperatures between 530 °C and 782 °C, depending on the zinc content, as shown in Figure 3. Liquid Metal Embrittlement (LME) is not a concern if forming is done in the absence of liquid zinc.G-25 Hensen et al. conducted several studies heating galvannealed 22MnB5 blanks to 900 °C, but forming after a pre-cooling stage. As seen in Figure 4, the microcrack depth is significantly reduced when the forming starts at lower temperatures.H-26
Figure 3: Temperature limit to ensure absence of Zn-rich liquid (re-created after Citations G-25 and G-26)
Figure 4: Crack depth reduces significantly if the forming is done at lower temperature (re-created after Citation H-26)
In the pre-cooled direct process, the blank is heated above the austenitization temperature (approximately 870-900 °C), and kept in the furnace for a minimum soaking time of 45 seconds. Once the blank leaves the furnace, it is first pre-cooled to approximately 500 °C and then formed. Typical 22MnB5 cannot be formed at this temperature due to two reasons: (1) its formability would be reduced and (2) forming could not be completed before the start of martensite formation at approximately 420 °C).K-22, V-8
The development of a “conversion-delayed” hot stamping grade (see PHS Grades with approximately 1500 MPa TS), commonly known as 20MnB8, addresses these concerns. This steel has lower carbon (0.20%, as the number 20 in 20MnB8 implies), but higher Mn (8/4 = 2%). . This chemistry modification slows the kinetics of the phase transformation compared with 22MnB5 – the critical cooling rate of 20MnB8 is approximately 10 °C/s. This allows the part to be transferred from pre-cooling stage to the forming die.
In the pre-cooled direct process, first the blank is heated to over 870-900 °C and soaked for at least 45 seconds. Then the blank is transferred to “pre-cooling stage” in less than 10 seconds. Precooling must be done at a rate over 20 °C/s, until the blank is cooled to approximately 500 °C. Then the part is transferred from the pre-cooling device to the press in less than 7 seconds. The forming is done in one hit in a hydraulic or servo-mechanical press, which can dwell at the bottom. The cooling rate after pre-cooling is advised to be over 40 °C/s. The final part may have zinc oxides and surface cleaning is required.K-22, V-8 The grade may be referred to as PHS950Y1500T-PS (Press Hardening Steel with minimum 950 MPa yield, minimum 1500 MPa tensile strength, Pre-cooled and Stamped).
Recently, several researchers have shown that pre-cooling may be used for drawing deeper partsO-6 or to achieve better thickness distribution of the final part.G-24 Since formed parts are typically removed from the press at approximately 200 °C, a pre-cooled part may require shorter time to quench, thus increasing the parts per minute.G-24
Multi-Step Process
(Blanking > Heating > Pre-cooling > Forming and Trimming > Air Quenching)
22MnSiB9-5 (see PHS Grades with approximately 1500 MPa TS) is a new steel grade developed by Kobe SteelH-27 for a transfer press process, named as “multi-step”. This steel has higher Mn and Si content, compared to typical 22MnB5. As quenched, the material has similar mechanical properties with 22MnB5. As of 2020, there is at least one automotive part mass produced with this technology and is applied to a compact car in Germany.G-27 Although critical cooling rate is listed as 2.5 °C/s, even at a cooling rate of 1 °C/s, hardness over 450HV can be achieved.H-27 This critical cooling rate allows the material to be “air-hardenable” and thus, can handle a transfer press operation (hence the name multi-step) in a servo press. This material is available only with Zn coating and requires a pre-cooling step before the transfer press operation.B-15 The grade may be referred to as PHS950Y1500T-MS (Press Hardening Steel with minimum 950 MPa yield, minimum 1500 MPa tensile strength, for Multi-Step process).
(Roll Forming > Heating > Quenching > Cut-to-length > Trimming & piercing)
Also known as inline hardening, this process is used to make profiles with constant cross sections and linear shapes. It is also possible to have closed profiles (tubes and similar) with this technology by adding a laser welding to the line (see Figure 5a). The process has been successfully used in many car bodies. Typical uses are: cross members, roof bows, side impact door beams, bumpers (with no sweep), front crash components and similar.G-28, H-28, F-16
Figure 5: Roll form PHS: (a) steps of the lineH-28, (b) photo of the induction heated area.G-28
The heating is typically done with induction heating, see Figure 5b. In one of the installations, the first induction coil operates at 25 kHz and the second at 200 kHz. The total heating power was approximately 700 kW and the line can run as fast as 6 m/s. It was found that if lubrication, speed and bending radius can be optimized, AlSi coated blanks could also be cold roll formed. However, they are not suitable for induction heating and may require a different process, such as form fixture hardening.K-23
Recently, voestalpine developed a Zn-coated steel for roll forming applications. This process also uses induction heating and water cooling. As the deformation is done at cold condition, the parts do not suffer from liquid metal embrittlement (LME).K-22
(Roll Forming (or tube blank) > Cut-to-length > Heating > Bending & forming > Quenching > Trimming / Piercing)
The main difference between roll form PHS and form fixture hardening is the secondary “hot bending and forming” in the press. Here, cold roll formed profiles are cut-to-length and heated in a furnace. Heated profiles are then transferred to a press die, where sweep bending and/or further forming operations are completed. The parts are subsequently quenched in the same press die, similar to direct process. A typical line layout can be seen in Figure 6a. The secondary forming makes variable sections possible, as seen in Figure 6b. As the parts are cold roll formed and furnace heated, uncoated, Zn-coated and AlSi-coated (with precautions not to crack AlSi) blanks may be used in this process.H-28, K-23
Figure 6: Form fixture hardening: (a) schematic of a lineK-23, (b) bumper beam of Ford Mustang (2004-2014) made by this process.L-26
Form fixture hardening parts have been used in low volume cars such as Porsche 911 or Bentley Mulsanne. In some cars, form fixture hardening was used to manufacture the A-pillar of the convertible (cabriolet) versions of high-volume cars, especially in Europe. Most of these applications involved uncoated boron alloyed tubes (similar to 22MnB5).H-28 The 5th generation Ford Mustang (2004-2014) had form fixture hardened bumper beams in the front and rear, as seen in Figure 6b.L-26 The form fixture hardening process allows for use of AlSi coatings, since the steel goes through a furnace rather than an induction hardening step. Special care must be taken in cold roll-forming process to ensure the AlSi coating is not damaged.K-23
(Cut-to-length tube or roll formed and welded profile > Heating > Pressure forming > Quenching > Piercing)
In hot gas metal forming, the tube or roll formed closed profile is heated first and placed onto a die set. The ends of the tube are sealed and pressurized gas or granular medium is forced inside the tubular blank. The forming forces are applied by the high pressure built inside the tube.C-16 It is also possible to end-feed material as in the case of (cold) tube hydroforming. After the deformation, the part is quenched either with water (form blow hardening) or by the air inside and the surface of the tool cavity (hot gas metal forming). In the latter case, similar to direct process, a water-cooling channel system inside the die inserts are typically required.K-23
Fraunhofer IWU has developed a hot gas metal forming setup in which both forming and quenching are done by compressed air. As shown in Figure 7a, the internal pressure can be increased to 70 MPa (700 bars) in only 6 seconds. The tools are cooled with internal cooling channels, Figure 7b. The parts produced with this technique have hardness values between 460 and 530 HV. Crashbox and camshafts are among the parts produced.L-27, N-16
Figure 7: Blow forming and quenching with air: (a) change of pressure in the tube and temperature of the tube, (b) simulation of heat transfer to the dies and cooling channels (recreated after Citation N-16)
In 2011, Spanish car maker SEAT published a study on form blow hardening process. In this study, they replaced the A-pillar and cantrail assembly of the SEAT León (Mk2, SOP 2005) with one form blow hardened part. The results were summarized asO-7:
- 7.9kg weight reduction per car,
- Sheet material utilization increased from 40 to 95%,
- Number of components in the assembly on one side of the car reduced from 5 to 2, and the roof rail was eliminated.
One advantage of this technology is the possibility to use the same die set for different wall thickness tubes. By doing so, parts can be produced for different variants of a car (i.e., coupe and cabrio, or North American spec. vs. emerging market spec.). This information applies to monolithic (i.e., same thickness throughout the tube) and tailor rolled/welded tubes as well.F-16 In 2017, tubular parts are hot gas formed by using 1900 MPa PHS tubes for customer trials.F-17
Since 2018, form blow hardening is being used in the Ford FocusB-16 and Jeep Wrangler.B-17 In the Ford Focus, a tailor rolled tube with thicknesses between 1.0 and 1.8 mm is used in Europe, whereas in China it is a monolithic (same thickness everywhere) 1.6 mm thick tube.F-16
3-Dimensional Hot Bending and Quenching (3DQ)
(Cut-to-length tube > Local induction heating > 3-D Bending > Direct Water Quenching > Piercing)
In the 3DQ process, a tubular profile with constant cross section is quickly heated by induction heaters. By using movable roller dies, the part is bent. As the material is fed, water is sprayed on the induction heated portion of the tube to quench and harden it. The schematic of the process and the material strength through the process is illustrated in Figure 8. It is also possible to replace the movable roller dies with an industrial robot to bend and twist the tubular part.T-25
Figure 8: Schematic of 3DQ system (re-created after Citation T-25)
In January 2013, Mazda announced that the ISOFIX connection in the rear seats of a Premacy MPV (known as Mazda 5 in some markets) model was produced by this method, as shown in Figure 9a.M-24 In 2016, Honda started production of the sports car NSX (known as Acura NSX in some markets). This vehicle’s A-pillars were produced by 3DQ process, as shown in Figure 9b.H-29
Figure 9: 3DQ applications: (a) Seat reinforcement of Mazda 5/PremacyM-24, (b) Acura NSX’s A-pillar.H-29
The technology has been used on uncoated blanks. In 2019, an academic study showed the feasibility of using Zn coated blanks in the 3DQ process.R-10
Steel Tube Air Forming process (STAF)
(Cut-to-length tube > Cold bending > Heating > Press Forming > Pressure Forming > Quenching > Piercing)
Steel Tube Air Forming process (STAF) is a modified and enhanced version of hot gas metal forming. In the STAF process, a metal tube is bent in a small press at room temperature. The preformed tube is transferred to the main press, where it is heated to the critical temperature using electrical conduction (Joule heating) by passing current through the tube. The first step creates the flanges where the press closes on the partially air blow formed tube. In the second step, air pressure completes the process by forming the desired cross section and overall shape.
As seen in Figure 10, the parts made with the STAF process can have a flange area for further welding/joining to other car body components. Some peripheral parts can be integrated into a single STAF part, improving productivity and manufacturing cost. The continuous closed cross section is created without the need for spot welding, improving stiffness and further reducing manufacturing costs. These factors combine to result in mass savings compared with conventional hot formed components, as indicated in Figure 11. F-18, F-41, F-42
Figure 10: The Steel Tube Air Forming process compared with other manufacturing approaches. STAF integrates flange formation without the need for additional spot welding.F-42 HSS stands for High-Strength Steel and may refer to conventional HSS or Advanced High-Strength Steels (AHSS).
Figure 11: The STAF process may reduce part count, assembled weight, and manufacturing complexity compared with other manufacturing approaches.F-41
The following video, kindly provided by Sumitomo Heavy Industries, highlights the STAF process along with associated benefits.F-41
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Press Hardened Steels
Overview
The initial press hardening steels of the 1970s were delivered bare, without a galvanized or aluminized layer for corrosion protection (i.e., uncoated). During the heating process, an oxide layer of FeOx forms if the furnace atmosphere is not controlled. Through the years, several coating technologies have been developed to solve the following problems of uncoated steelsF-14, F-33:
- Scale formation, which causes abrasive wear and requires a secondary shotblasting process before welding,
- Decarburization, which leads to softening close to the surface,
- Risk of corrosion.
The first commercially available coating on press hardening steels was patented in 1998. The coating was designed to solve the scaling problem, but it also offered some corrosion resistance.C-24 Since the coating composition is primarily aluminium, with approximately 9% silicon, it is usually referred to as AlSi, Al-Si, or AS.
Coating thickness is nominally 25 μm (75 g/m2) on each side and referenced as AS150. A more recent offering is a thinner coating of 13 μm (AS80).A-51 The AS coating requires a special heating curve and soaking time for better weldability, corrosion resistance and running health of the furnace. Most OEMs now include furnace dew point limitations to reduce/avoid hydrogen embrittlement risk.
In 2005, Volkswagen was looking for a method to manufacture deep drawn transmission tunnels and other complex-to-form underbody components using press hardened steels. Although AS coatings were available, parts could not be formed to the full draw depth using the direct process, and AS coated blanks cracked during the cold forming portion of the two-step hybrid process. Using uncoated blanks led to severe scale formation, which increased the friction coefficient in hot forming. For this particular problem, a varnish coating was developed. The coating was applied at a steel mill, and shipped to Volkswagen’s stamping plant. The parts were first cold pre-formed and then heated in a furnace, as seen in Figure 1a. Hot pre-forms were then deep drawn to tunnels. As shown in Figure 1b, scale formed on parts which did not have the coating. A varnish coated blank could be cold formed without any scale, Figure 1c.S-63, F-34 Since then, some other varnish coatings also have been developed.
Figure 1: Transmission tunnel of 2005 Volkswagen Passat: (a) hot forming of pre-form, and final parts: (a) uncoated blank would suffer from scaling, (c) scale-free parts can be formed from varnish-coated blanks.F-34
In car bodies, components that are sealed from external moisture are referred to as dry areas. These areas have low risk of corrosion. Areas that may be exposed to moisture are wet areas. Precautions must be taken to avoid corrosion of the sheet metal, such as using galvanized or pre-coated steel. Sealants can also be applied to joints to keep out moisture. The presence of humidity in these areas increases the risk of forming a galvanic cell, leading to accelerated corrosion. These areas have higher risk of corrosion and may require additional measures. Figure 2 shows dry and wet areas. In this figure, parts colored with yellow may be classified as wet or dry, depending on the vehicle design and the OEMs requirements.G-41
Figure 2: Dry and wet areas in a car body.G-41
An estimated ~40% of press hardened components are in dry areas. Thus, high corrosion protection is desired in the 60% of all press hardened components which are employed in wet areas.B-48 Zn-based coatings are favored for their cathodic protection, but require tight process control. The first commercial use of Zn-coated PHS was in 2008, using the indirect process.P-20 Since then, direct forming of Zn-coated PHS has been studied. When direct formed, furnace soaking temperature and time must be controlled carefully to avoid deep microcracks.G-41, K-20 Recently developed are two new Zn-coated press hardening steel grades, 20MnB8 and 22MnSiB9-5, both reaching approximately 1500 MPa tensile strength after processing. Using grades requires a pre-cooling process after the furnace to solidify the Zn-based coating. 20MnB8 can be direct hot formed to final shape, whereas 22MnSiB9-5 can be formed in a transfer press in the “multi-step” process.K-21, H-27
Depending on the coating type and thickness, the process type, controls and investment requirements may change significantly. For example, some press hardening lines may be designed to form blanks with only Al-based coatings. Table 1 summarizes the advantages and disadvantages of several coating systems.
Table 1: Summary of coatings available for press hardening steels.
Uncoated Blanks
The earliest press hardening steels did not have any coating on them. These steels are still available and may be preferred for dry areas in automotive applications. If the steel is uncoated and the furnace atmosphere is not controlled, scale formation is unavoidable. Scale is the term for iron oxides which form due to high temperature oxidation. Scale thickness increases as the time in furnace gets longer, as seen in Figure 3. Scale has to be removed before welding, requiring a shotblasting stage. Thicker scale is more difficult and more costly to remove.M-53 Early attempts to reduce (if not avoid) scale formation saw the use of an inert-gas atmosphere inside the furnace.A-52 Today, a mixture of nitrogen (N2) and natural gas (CH4) is typically used.F-35 In China, at least one tier supplier is using a vacuum furnace to prevent scale formation.A-68
Figure 3: Oxide layer (scale) on press hardened steel after: (a) fast resistance heating (10 seconds in air), (b) furnace heating (120 seconds in air).M-53
While heating uncoated steel in the furnace, if the conditions are favorable for iron (Fe) oxidation, carbon (C) may also be oxidized. When the carbon is oxidized, layers close to the surface lose their carbon content as gaseous carbon monoxide (CO) and/or carbon dioxide (CO2) is produced.S-87 The depth of the “decarburization layer” increases with dwell time in the furnace, until an oxide layer (scale) formed. Scale acts as a barrier between the bare steel and atmosphere. As the carbon is depleted in the “decarburization layer”, the hardness of the layer is decreased, as seen in Figure 4. Decarburization is usually undesirable since it lowers the strength/hardness and may negatively affect fatigue life.C-26
Figure 4: Hardness distribution of an uncoated steel after 6 minutes in a 900 °C furnace, showing hardness decrease as the surface layers lose their carbon. Image recreated after C-26.
Several methods are available to improve the corrosion resistance of uncoated PHS parts:
- E-coating after welding, before painting is a typical step of car body manufacturing, for rustproofing.
- If descaling can be done by using chromium shots (in shotblasting), a thin film of chromium-iron may grow on the surface and improve the corrosion resistance.F-14
- Vapor galvanizing (also known as Sherardizing) of uncoated steel after descaling, an experimental study described in Citation G-42.
- Electro-galvanizing after hot stamping, as described in Citation A-68.
- Change the base metal chemistry to one that is more oxidation resistant.L-60 Figure 5 compares the shiny non-oxidized surface appearance of parts made from this grade with that made from a conventional uncoated press hardening grade on the same production line with the same processing conditions.W-28
Figure 5: Oxidation resistant PHS grades may not need descaling or coatings for sufficient corrosion resistance.W-28
Aluminium-Based Coatings
The first commercially available coating on press hardening steels was patented by Sollac (now part of ArcelorMittal) in 1998. This coating was designed to address the scaling problem, but also offers some barrier corrosion resistance.C-24 The nominal coating composition is 9-10 wt.% Si, 2-4 wt.% Fe, with the balance Al.L-39 The coating may be referred to as AlSi, Al-Si, AluSi or more commonly AS. Nominal as-delivered coating thickness is 25 μm (approximately 75 g/m2) on each side, and is usually referred to as AS150, with 150 referencing the total coating weight combining both sides, expressed as g/m2. More recently, a thinner coating of 13 μm (30-40 g/m2 on each side, AS60 or AS80) is now commercially available.A-51 When AS coated blanks are “tailor rolled,” the coating thickness is also reduced in a similar percentage of the base metal thickness reduction. Corrosion protection is similarly reduced, and furnace parameters need to be adjusted accordingly.
As delivered, AS150 has a coating thickness of 20-33 μm and a hardness of approximately 60 HV. The “interdiffusion layer” (abbreviated as IDL) has a high hardness and low toughness at delivery, as seen in Figure 6a. Due to the brittle nature of the IDL, AS coated blanks cannot be cold formed unless very special precautions are taken. During heating, iron from the base metal diffuses to the coating forming very hard AlSiFe (or AlFe) layers close to surface. At the same time, Al and Si of the coating diffuse to the IDL, growing it in thickness and reducing its hardness, Figure 6b. Earlier studies have shown that heating time (and also furnace temperature) has direct effect on the final thickness of IDL, as shown in Figure 7. Once the IDL thickness surpasses approximately 16 to 17 μm, the welding current range (ΔI = Iexpulsion – Imin) may be well below 2 kA.V-15, V-21, W-34 The dwell time must be long enough to ensure proper surface roughness (see Figure 6b) for e-coatability.M-27, T-40 Figure 10 summarizes the heating process window of AS coatings. The process window may change with base metal and coating thicknesses.
Figure 6: AS coating micrographs: (a) as-delivered, (b) after hot stamping process (re-created after V-15, V-21, W-34, G-32)
Figure 7: IDL thickness variation with furnace dwell time (Image created by B-55 using raw data from V-21, G-32, K-41.)
Hydrogen induced cracking (HIC, also known as hydrogen embrittlement) has been a major problem for steels over 1500 MPa tensile strength. AS coated steels may have higher diffusible hydrogen, when delivered, due to the aluminizing process occurring at 680 °C. In addition, AS coated grades may have a hydrogen absorption rate up to three times higher during heating.C-27 To reduce the hydrogen diffusion, it is essential to control the heating process (both heating rate and dew point in the furnace). AS coated blanks absorb hydrogen at room temperature; however, this happens at much lower rates than uncoated or Zn-coated blanks.J-21 Diffusible hydrogen can be removed from the press hardened part by re-heating the part to around 200 °C for 20 minutes or longer, in a process called de-embrittlement.V-21, G-32, G-43, J-21
For the abovementioned reasons, AS coated higher strength grades (i.e., PHS1800 and over) are required to have precise “dew point regulations” during the heating in furnace. Their final properties, especially elongation and bending angle, may be guaranteed only after bake hardening, as shown in Figure 8.B-32 Paint baking is standardized in Europe as a treatment for 20 minutes at 170 °C, which may act like a de-embrittlement treatment.E-10 Some OEMs also require dew point control and “subsequent de-embrittlement treatment” for AS coated PHS1500.
Figure 8: Effect of diffusible hydrogen (Hdiff) on mechanical properties of: (a) uncoated PHS2000, (b) AS coated PHS2000 in an uncontrolled furnace atmosphere (B-55 using raw data from C-27).
Another method to reduce the risk of hydrogen embrittlement is to adjust the coating composition. The bath chemistry for a standard AlSi coating consists of up to 90% aluminum, about 8% to 11% silicon and a maximum of 4% iron. Adding a maximum of 0.5% alkaline earth metals, like magnesium, for example has been shown to result in 40% less hydrogen diffusion into steel.R-29, T-45
Although not common in the industry, Al-Zn and Zn-Al-Mg based coatings have also been developed for press hardening processes.F-14 Recently introduced is an aluminium-silicon coating with magnesium additions. When oxidized with water vapor, Mg releases less H2 and thus may reduce the diffusible hydrogen.S-88
AS coatings may cause costly maintenance issues in roller hearth furnaces, as the coating may contaminate the rollers.B-14 Special care has to be taken to avoid the issue or prolong the maintenance intervals.
Zinc-Based Coatings
AS coatings provide some corrosion protection, known as “barrier protection”, as the coating forms a barrier between the oxidizing environment and the bare steel. It is quite common in Europe for a car to have 12 years corrosion protection warranty. To achieve such corrosion resistance, a typical car may have over 85% of its components galvanized.S-89
The use of Zn-coated PHS has been relatively low, compared to AS coated and uncoated grades. In 2015, 76% of the PHS sold in EU27+Turkey was AlSi coated. In these markets, 18% of the PHS sold was uncoated and only 6% was Zn coated.D-20 This can be attributed to the susceptibility of Zn-coated PHS to Liquid Metal Embrittlement (LME, also known as Liquid Metal Assisted Cracks (LMAC) and Liquid Metal Induced Embrittlement (LMIE)).C-28, L-46
After heating and soaking in the furnace, the base metal should be in the austenitic phase. During heating, the Zn coating reacts with the base metal and forms a thin solid layer of body-centered-cubic solid solution of Zn in α-Fe, shown as α-Fe(Zn) in Figure 9. During deformation, a microcrack can be initiated in this layer at the grain boundaries of the austenite in the base metal, as indicated in Figure 9a. As the crack propagates, zinc from the α-Fe(Zn) layer diffuses along the austenite grain boundary and combines with iron from the base steel to form additional α-Fe(Zn), Figure 9b. Cracks propagate through the weak a-Fe(Zn) grain boundary layer, allowing liquid zinc (with diffused iron) to advance into the capillary crack (Figure 9c). After quenching, the base metal transforms to martensite and the liquid Zn transforms to a hard and brittle intermetallic phase, Γ-Fe3Zn10.C-28
Figure 9: Schematic illustration of microcrack formation. (re-created based on C-28.)
To avoid LME, three methods can be employedK-20:
- Forming in the absence of liquid Zn,
- Reducing stress level,
- Reducing material susceptibility.
There are no breakthroughs to address the last two items. Forming a part in the absence of liquid Zn involves either of two process routes: (1) Indirect press hardening (also known as form hardening), or (2) Pre-cooled direct processes.
In the direct forming of Zn-coated blanks, with or without pre-cooling, microcracks in the base metal may be observed. Microcracks less than 10 μm into the base metal does not affect the fatigue strength of the part.K-20 Microcrack depth is a function of coating thickness, furnace conditions (temperature and dwell time, see Figure 10), forming severity and forming temperature. It may be possible to direct form galvannealed (GA coated) blanks.
The boiling point of pure zinc (907 °C) is very close to the austenitization temperature of 22MnB5 (885 °C), so the heating process window of Zn-coated blanks must be controlled precisely. When the furnace dwell time is too short, deeper microcracks may be observed. When the furnace dwell time is too long, corrosion performance may be degraded. Thus, heating process window of Zn-coated blanks is significantly narrower than that of AS-coated blanks.B-14, S-90
Figure 10: Heating process window of AS and Zn coatings (representative data, may not be accurate for all sheet and coating thicknesses, re-created based on B-14, S-90.
Zn-based coatings may result in very low diffusible hydrogen after press hardening. In one studyJ-21, no diffusible hydrogen was detected, as long as the furnace dwell times are shorter than 6 minutes. Even after 50 minutes in the furnace, diffusible hydrogen was found to be around 0.06 ppm. Zn coatings do not act as a barrier for hydrogen desorption (losing H through the surface). Even at room temperature, Zn coated blanks may lose most of the diffusible hydrogen within a few days (also referred to as aging).
Figure 11: Evolution of galvanized coating: (a) as delivered: Ferrite+Pearlite in base metal, almost pure Zn coating with Al-rich inhibition layer, (b) at high temperatures: austenite in base metal + α-Fe(Zn) and liquid Zn + surface oxides, (c) after press hardening: martensite in base metal + α-Fe(Zn) and Γ-phase coatings + surface oxides. The oxides are removed prior to welding and painting.J-21
Zn-based coatings may have a yellowish color after hot stamping. The surface oxides have to be removed before welding. This is typically done by shotblasting.
PHS blanks with a ZnNi coating were previously available. The ZnNi coating provided a low friction coefficient, a large process window in the furnace, the ability to be cold formed (indirect or two-step hybrid processes were also possible) and decreased susceptibility to LME.B-56 ZnNi coated PHS was used in the rear rail of the Opel Adam city carH-57 for a short period, until the coating was discontinued.C-29
Varnish Coatings
Another method to avoid scaling and decarburization is to apply varnish coatings. In this method, uncoated steel can be either coil coated or blanks can be manually coated with the paint-like varnish coatings.B-14 These coatings may also be known as “paint-type” or “sol-gel”.
Figure 12: Manual application of a varnish coating.F-34
Depending on the type of coating, they may allow very fast heating – including induction and conduction heating with electric current. Since the coating does not require time to diffuse, furnace heating may be completed in less than 2 minutes.F-34 Again, depending on the type, surface conditioning may not be required before welding or e-coating.B-14
They were used in automotive industry between 2005 and 2010. By 2015 there were four different types of varnish coatings, some of which are now discontinued.B-14 These coatings may be useful for prototyping and low volume production.
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