Bake Hardenable

Bake Hardenable

BH Grades

Bake Hardenable (BH) steels grades are conventional High Strength Steels that exhibit a Bake Hardening Effect. BH steels exhibit an increase in yield strength after room-temperature stamping followed by processing through a thermal cycle comparable to the time-temperature profile used in paint curing (or baking) – approximately 170 °C for 20 minutes. Bake hardenability is characterized by determining the Bake Hardening Index.

Bake Hardenable steel grades have yield strength at shipment from the steel mills of 180 MPa to 300 MPa (approximately 25 ksi to 45 ksi). The grades at the lower strength levels are capable of being produced with a Class A surface finish and are used in applications where dent resistance is desired in thin sheet steel. Applications for the higher strength BH steels include structural parts where Class A surface is not required. The higher strength after forming and baking is the reason automakers might use these in body structure applications, potentially contributing to vehicle lightweighting efforts.

These grades work harden approximately 30 MPa when 2% strain is introduced, either from stamping or during a tensile test, which is similar to dent resistant IF-HS. In contrast to IF-HS, the paint-bake cycle after forming results in an additional yield strength increase. The minimum strength increase from baking is specified by some automakers as 20 MPa to 35 MPa, measured after applying a defined level of strain.

Higher yield strength directly improves the dent performance. Even though BH grades and their non bake hardening counterpart IF-HS grades may have similar yield strength and thickness after forming, bake hardenable steels will show superior dent resistance due to the increase in yield strength from the paint baking operation.

Ferrite is the main microstructural phase of BH steels. The strengthening from the paint bake cycle is due to the controlled amount of carbon remaining in solid solution (on the order of 25 ppm) when the steel leaves the production mill. At the baking temperatures after the part is formed, the dissolved carbon migrates to pin any free dislocations created from stamping. This increases the yield strength of the formed part for increased dent resistance. Formability does not suffer, since the strength increase occurs after stamping.

Most Advanced High Strength Steel (AHSS) grades also exhibit a Bake Hardening Effect, achieving yield strength increases of 40 MPa to 120 MPa from an appropriate thermal cycle. AHSS grades are not categorized with traditional bake hardenable steels, since their primary characteristics and applications are typically, but not exclusively, different. One exception are some Dual Phase (DP) steels available with a Class A surface, which are used as skin panels to combine excellent dent resistance with lightweighting benefits.

Some of the specifications describing uncoated Bake Hardenable (BH) steel are included below, with the grades typically listed in order of increasing minimum yield strength and ductility. Different specifications may exist which describe uncoated or coated, or steels of different strengths.

  • ASTM A1008M, with the terms BHS 26 [180], BHS 31 [210], BHS 35 [240], BHS 41 [280], BHS 44 [300]A-25
  • EN10268, with the terms HC180B, HC220B, HC260B, and HC300LAD-3
  • JIS G3135, with the term SPFC340HJ-3
  • JFS A2001, with the terms JSC270H, JSC340HJ-23
  • VDA239-100, with the terms CR180BH, CR210BH, CR240BH, and CR270BHV-3

 

Bake Hardening Effect

Bake Hardenable Steel Grades and most AHSS grades exhibit a Bake Hardening Effect, meaning that there is an increase in yield strength after room-temperature stamping followed by processing through a thermal cycle comparable to the time-temperature profile used in paint curing (or baking) – approximately 170 °C for 20 minutes.

The degree to which a sample is bake hardenable is characterized by the Bake Hardening Index.

In Bake Hardenable Steel Grades, solid solution hardening elements like phosphorus, manganese, and silicon are used to achieve the desired initial strength. For AHSS, the initial strength is determined by the balance and volume fraction of microstructural components like ferrite, bainite, retained austenite, and martensite. In both cases, a specifically engineered amount of dissolved carbon in the ferritic matrix causes an additional increase in the yield strength through controlled carbon aging during the paint-bake thermal cycle. The bake hardening process in AHSS grades is more complex, and results in substantially higher values of the Bake Hardening Index.

Figure 1 shows the work hardening and bake hardening increases for samples of three High-Strength steel grades having the same as-received yield strength prior to 2% pre-straining and baking. The HSLA steel shows little or no bake hardening, while AHSS such as DP and Transformation Induced Plasticity (TRIP) steels show a large positive bake hardening index. The DP steel also has significantly higher work hardening than HSLA or TRIP steel because of higher strain hardening at low strains. No aging behavior of AHSS has been observed due to storage of as-received coils or blanks over a significant length of time at normal room temperatures. Hence, significant mechanical property changes of shipped AHSS products during normal storage conditions are unlikely.

The higher bake hardening index (BHI) of AHSS grades DP 600 and TRIP 700 is also shown in Figure 2. While BHI is determined at a prestrain of 2%, this graph indicates that even higher levels of bake hardenability can be achieved with increasing strain. In a stamping where most areas have more than 2% strain, combining this higher bake hardenability with the increased work hardening that occurs with increasing strain results in a formed panel having a strength markedly higher than the incoming flat steel. This is beneficial for crash energy management.

Figure 1: Comparison of work hardening (WH) and bake hardening (BH) for TRIP, DP, and HSLA steels given a 2% prestrain. S1, K3

Figure 1: Comparison of work hardening (WH) and bake hardening (BH) for TRIP, DP, and HSLA steels given a 2% prestrain. S-1, K-3

 

Figure 2: Bake hardening responses of several HSS and AHSS products with varying pre-strain, reproduced from Figure 3 in Citation B-6. The bracketed numbers after each grade are references within the cited paper.

Figure 2: Bake hardening responses of several HSS and AHSS products with varying pre-strain, reproduced from Figure 3 in Citation B-6. The bracketed numbers after each grade are references within the cited paper.

 

Bake Hardenability of Exposed Quality Dual Phase Steels

Dent resistance is a function of the yield strength in the formed panel after it completes the paint baking cycle. Based on this premise, grades with higher bake hardenability, such as AHSS, should have substantially higher dent resistance. Application of AHSS grades to capitalize on improved dent resistance also requires their production at the desired thickness and width along with surface characteristics appropriate for Class A exposed quality panels. Some DP steels meet these tight requirements specified by the automotive industry.

A recent studyK-49 highlights this improved dent resistance. This work presents the experimental results and associated numerical investigation of the dent testing of DP270Y490T, a DP steel grade with 490 MPa minimum tensile strength. Tests performed to the SAE J2575 procedureS-7 measure the resultant dent depth after testing, so therefore smaller depths indicate improved performance. Compared with samples not processed through a bake hardening cycle, dent depth reductions occur with hotter and longer cycles, as shown in Figure 3. Increasing temperature plays a more significant role in dent depth reduction than increasing time. This work also reinforces that bake hardenability must be incorporated into simulation models in order to improve the accuracy of dent resistance predictions.

Figure 3: Dent resistance of DP270Y490T according to SAE J2575S-7* as a function of baking test conditions.K-49  Lower dent depth indicates better dent resistance.

Figure 3: Dent resistance of DP270Y490T according to SAE J2575S-7 as a function of baking test conditions.K-49 Lower dent depth indicates better dent resistance.

 

Measuring The Bake Hardenability Index

Bake hardenability is characterized by determining the Bake Hardening Index, or BHI.

The Bake Hardening Index (BH2) is determined by taking a conventional tensile test sample and pulling it to 2% strain. This is known as a 2% pre-strain. The sample is then put into an oven for a thermal cycle designed to be typical of an automotive paint curing (paint baking) cycle: 170 °C for 20 minutes. The temperature and time may be different depending on the end-user specifications.

Some companies may specify BH0, which uses the same thermal cycle without the 2% pre-strain. BH5 or BH10 (5% or 10% pre-strain, respectively) may also be reported.

The experimental procedure and calculation of BH2 is standardized in EN 10325D-4 and JIS G 3135J-3, and is similarly described in several other specifications.

Figure 4 defines the measurement for work hardening (B minus A), unloading to C for baking, and reloading to yielding at D for measurement of bake hardening (D minus B).  Note that the bake hardening index shown here is measured up to the lower yield point, which is consistent with the EN 10325 definition.  JIS G 3135 prescribes the use of the upper yield point.

Figure 4: Measurement of work hardening index and bake hardening index.

Figure 4: Measurement of work hardening index and bake hardening index.  BHI is measured using the lower yield point in EN 10325D-4 and with the upper yield point in JIS G 3135J-3.

 

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Submitting Your Content

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Fundamentals

Please keep in mind the following fundamentals before you start writing your blog.

  • Your submission must contain references to Advanced High-Strength Steel (AHSS) in vehicle applications. Note that the name of our blog is AHSS Insights, therefore, readers will be expecting to expand their AHSS knowledge base.
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We will notify you in advance as to when your entry is scheduled to publish. We strongly encourage you to use your social contact network to share the blog article. Your shares should include our blog hashtag, #AHSSblog.

 

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We are always looking for video and animations to help support existing articles with visual information.  If you think you have something that would enhance an article, please contact us at the email link above.  You can send us a link to what you have, and we will review it.  Note, the video must be owned by you in order to be considered and not contain any sales pitches.  If we agree to use it, we’ll need to receive the original video file so that it can be uploaded directly to our site.  You/your company will receive full citation as a the source of the video.  Have a look at our Roll Forming page to see an example of how we have used a video received from Shape Corp.

 

We look forward to receiving your submission. It is our pleasure to collaborate on AHSS education with you. Thank you!

M-Value

M-Value

M-Value, Strain Rate Sensitivity

The strengthening of some metals changes with the speed at which they are tested. This strain-rate sensitivity is described by the exponent, m, in the modified power law equation:

 

where έ is the strain rate and m is the strain rate sensitivity.

To characterize the strain rate sensitivity, medium strain rate tests were conducted at strain rates ranging from 10-3/sec (commonly found in tensile tests) to 103/sec. For reference, 101/sec approximates the strain rate observed in a typical stamping. Both yield strength and tensile strength increase with increasing strain rate, as indicated Figures 1 and 2.

Figure 1: Influence of Strain Rate on Yield Strength

Figure 1: Influence of Strain Rate on Yield Strength.Y-1

 

Figure 2: Influence of Strain Rate on Tensile Strength

Figure 2: Influence of Strain Rate on Tensile Strength.Y-1

 

Up to a strain rate of 101/sec, both the YS and UTS only increased about 16-20 MPa per order of magnitude increase in strain rate. These increases are less than those measured for low strength steels. This means the YS and UTS values active in the sheet metal are somewhat greater than the reported quasi-static values traditionally reported. However, the change in YS and UTS from small changes in press strokes per minute are very small and are less than the changes experienced from one coil to another.

The change in n-value with increase in strain rate is shown in Figure 3. Steels with YS greater than 300 MPa have an almost constant n-value over the full strain rate range, although some variation from one strain rate to another is possible.

Figure 3: Influence of Strain Rate on n-value

Figure 3: Influence of Strain Rate on n-value.Y-1

 

Similar behavior was noted in another studyB-22 that included one TRIP steel and three DP steels. Here, DP1000 showed a 50% increase in yield strength when tested at 200/sec compared with conventional tensile test speeds. Strain rate has little influence on the elongation of AHSS at strain rates under 100/sec.

Relationship between strain rate and yield strength (left) and elongation (right)

Figure 4: Relationship between strain rate and yield strength (left) and elongation (right). Citation B-22, as reproduced in Citation D-44

 

Figure 5 shows the true stress-true strain curves for a processed Press Hardened Steel tested at different strain rates. The yield stress increases approximately five MPa for one order of magnitude increase in strain rate.

Figure 4: True stress-strain curves at different strain rates for 1mm thick Press Hardening Steel (PHS) after heat treatment and quenching.

Figure 5: True stress-strain curves at different strain rates for 1mm thick Press Hardening Steel (PHS) after heat treatment and quenching.V-1

 

The tensile and fracture response of different grades is a function of the strain rate and cannot be generalized from conventional tensile tests.  This has significant implications when it comes to predicting deformation behavior during the high speeds seen in automotive crash events.  See our page on high speed testing for more details.

Bake Hardenable

Crash Management

In addition to enhanced formability, Advanced High-Strength Steels (AHSS) provide crash energy management benefits over their conventional High-Strength Steel (HSS) counterparts at similar strength levels.  Higher levels of work hardening and bake hardening at a given strength level contribute to this improvement in crash performance.

The energy required for plastically deforming a material (force times distance) has the same units as the area under the true stress-true strain curve.  This applies to all types of plastic deformation – from that which occurs during tensile testing, stamping, and crash.  The major difference between these is the speed at which the deformation takes place.

As an example, consider the press energy requirements of two grades by comparing the respective areas under their true stress – true strain curves.  The shape and magnitude of these curves are a function of the yield strength and work hardening behavior as characterized by the n-value when tested at conventional tensile testing speeds.    At the same yield strength, a grade with higher n-value will require greater press energy capability, as highlighted in Figure 1 which compares HSLA 350/450 and DP 350/600. For these specific tensile test results, there is approximately 30% greater area under the DP curve compared with the HSLA curve, suggesting that forming the DP grade requires 30% more energy than required to form a part using the HSLA grade.

Figure 1: True stress-strain curves for two materials with equal yield strength.T-3

Figure 1: True stress-strain curves for two materials with equal yield strength.T-3

 

The high degree of work hardening exhibited by DP and TRIP steels results in higher ultimate tensile strength than that exhibited by conventional HSS of similar yield strength. This provides for a larger area under the true stress-strain curve.  Similarly, when panels are formed from these grades, the work hardening during forming leads to higher in-panel strength than panels from HSS of comparable yield strength, further increasing the area under the stress-strain curve, ultimately resulting in greater absorption of crash energy.

Finally, the high work-hardening rate better distributes strain during crash deformation, providing for more stable, predictable axial crush that is crucial for maximizing energy absorption during a front or rear crash event.

Many AHSS are bake hardenable. The relatively large BH effect also increases the energy absorption capacity of these grades by further increasing the area under the stress-strain curve. The BH effect adds to the work hardening imparted by the forming operation. Conventional HSS do not exhibit a strong BH effect and therefore do not benefit from this strengthening mechanism.

Figure 2 illustrates the difference in energy absorption between DP and TRIP steels as a function of their yield strength determined at quasi-static tensile testing speeds.

Figure 2: Absorbed energy for square tube as function of quasi-static yield strength. T-2

Figure 2: Absorbed energy for square tube as function of quasi-static yield strength.T-2

 

Figure 3 shows calculated absorbed energy plotted against total elongation for a square tube component. The absorbed energy remains constant for the DP and TRIP steels but the increase in total elongation allows for formation into complex shapes.

Figure 3: Calculated absorbed energy for a square tube as a function of total elongation.T-2

Figure 3: Calculated absorbed energy for a square tube as a function of total elongation.T-2

 

For certain parts, conventional steels may have sufficient formability for stamping, yet lack the required ductility for the desired crash failure mode and will split prematurely rather than collapsing in a controlled manner. AHSS grades improve energy absorption by restoring a stable crush mode, permitting more material to absorb the crash energy.  The increased ductility of AHSS grades permit the use of higher strength steels with greater energy absorbing capacity in complex geometries that could not otherwise be formed from conventional HSS alloys.

Stable and predictable deformation during a crash event is key to optimizing the steel alloy selection. The ideal profile is a uniform folding pattern showing progressive buckling with no cracks (Figure 4).

Figure 4: Deformation after axial crushing.A-49

Figure 4: Deformation after axial crushing.A-49

 

Achieving crack-free folds is related to the local formability of the chosen alloy.  Insufficient bendability can lead to early failure (Figure 5).  Research to determine proper simulation inputs with physical testing for verification.

Figure 5: Three-point bend testing of two DP980 products having different folding and cracking behavior resulting from different microstructures and alloying approaches.B-12

Figure 5: Three-point bend testing of two DP980 products having different folding and cracking behavior resulting from different microstructures and alloying approaches.B-12

 

 

High Strain Rate Property Test Methods

for Steel and Competing Materials

Tensile testing occurs at speeds that are 1000x slower than typical automotive stamping rates. Furthermore, automotive stamping is done at speeds that are 100x to 1000x slower than crash events.  Stress-strain responses change with test speed – sometimes quite dramatically.

The m-value is one parameter to characterize this effect, since it is a measure of strain rate sensitivity.  Generally, steel has more favorable strain rate effect properties compared with aluminum, but this is also a function of alloy, test temperature, selected strain range, and test speed. L-20

These reasons form the background for the need to characterize the intermediate and high strain rate behavior of AHSS.

Bake Hardenable

Forming Limit Curves (FLC)

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If all stampings looked like a tensile dogbone and all deformation was in uniaxial tension, then a tensile test would be sufficient to characterize the formability of that metal. Obviously, engineered stampings are much more complex.  Although a tensile test characterizes one specific strain path, a Forming Limit Curve (FLC) is necessary to have a map of strains indicating the onset of critical through-thickness necking for different linear strain paths. The strains which make up the FLC represent the limit of useful deformation. Calculations of safety margins are based on the FLC (Figure 1).

Figure 1: General graphical form of the Forming Limit Curve E-2 

Figure 1: General graphical form of the Forming Limit Curve.E-2

 

Picturing a blank covered with circles helps visualize strain paths.  After forming, the circles turn into ellipses, with the dimensions related to the major and minor strains. This forms the basis for Circle Grid Strain Analysis.

 

Generating Forming Limit Curves from Equations

Pioneering work by Keeler, Brazier, Goodwin and others contributed to the initial understanding of the shape of the Forming Limit Curve, with the classic equation for the lowest point on the FLC (termed FLC0) based on sheet thickness and n-value. Dr. Stuart Keeler was the Technical Editor of these AHSS Guidelines through Version 6.0, released in 2017.

Equation 1

 

These studies generated the left hand side of the FLC as a line of constant thinning in true strain space, while the right hand side has a slope of +0.6, at least through minor (engineering) strains of 20%.

Evidence accumulated over many decades show that this approach to defining the Forming Limit Curve is sufficient for many applications of mild steels, conventional high strength steels, and some lower strength AHSS grades like CR340Y/590T-DP. However, this basic method is insufficient when it comes to creating the Forming Limit Curves for most AHSS grades and every other sheet metal alloy.  Grades with significant amounts of retained austenite experience significant deviations from these simple estimates.H-23, S-61  In these cases, the FLC must be experimentally determined.

Additional studies found correlation with other properties including total elongation, tensile strength, and r-valueR-8, P-19, G-23, A-45, A-46, H-23 with some of these attempting to define the FLC by equations.

 

Experimental Determination of Forming Limit Curves

ASTM A-47 and ISO I-16 have published standards covering the creation of FLCs. Even within these standards, there are many nuances left for interpretation, primarily related to the precise definition of when a neck occurs and the associated limiting strains.

There are two steps in creating FLCs: Forming the samples and measuring the strains.

Forming sheet specimens of different widths uses either a hemispherical dome (Nakajima or Nakazima method N-14) or a flat-bottom punch (Marciniak method M-22) to generate different strain paths from which critical strains are determined. The two methods are not identical due to the different strain paths generated from the punch shape.  These differences may not be significant for many lower strength and conventional High-Strength Steels, but may deviate from each other at higher strengths or with advanced microstructures.  Figure 2 highlights samples formed with the Nakajima method.

Figure 2:  Forming limit curves can be created by deforming multiple samples of different widths. Narrow strips on the left allow metal to flow in from the unconstrained edges, creating a draw deformation mode leading to strains that plot on the left side of the FLC.  Fully constrained samples, shown on the rightE-2, create a stretch deformation mode leading to strains that plot on the right side of the FLC.

Figure 2:  Forming limit curves can be created by deforming multiple samples of different widths. Narrow strips on the left allow metal to flow in from the unconstrained edges, creating a draw deformation mode leading to strains that plot on the left side of the FLC.  Fully constrained samples, shown on the rightE-2, create a stretch deformation mode leading to strains that plot on the right side of the FLC.

 

Generally, strains are measured using one of two methods.  The first approach involves covering the initially flat test samples with a grid pattern of circles, squares, or dots of known diameter and spacing to measure the strains associated with deformation.  An alternate approach is based on Digital Image Correlation (DIC), where a camera tracks the movement of a random speckle pattern applied prior to forming.W-26, H-22, M-21  DIC methods are directly suited for use with stress-based FLCs.

 

Differences between Forming Limit Curves

and Forming Limit Diagrams

Often, the terms Forming Limit Curve (FLC) and Forming Limit Diagram (FLD) are used interchangeably. Perhaps a better way of categorizing is to define the components and what they encompass.  This is somewhat of a simplification, since detailed interactions are known to occur.

  • The Forming Limit Curve is a material parameter reflecting of the limiting strains resulting in necking failure as a function of strain path. It is a function of the metal grade, thickness, and sheet surface conditions, as well as the methods used during its creation (hemispherical/flat punch, test speed, temperature). It is applicable to any part shape.
  • Deforming a flat sheet into an engineered stamping results in a formed surface with strains as a function of the forming conditions like local radii, lubrication, friction, and of course part geometry. These strains are essentially independent of the chosen metal grade and thickness.  Plotting these strains allows for a relative assessment of which strains are higher than others, but no judgment can be made on “how high is too high?”
  • The Forming Limit Diagram is a combination of the Forming Limit Curve (a material property) and the strains (reflecting part geometry and forming conditions). The FLD provides guidance on which areas of the formed part requires additional attention to achieve robust stamping conditions.  Creating a subsequent FLD may be warranted when conditions change, since changes to the sheet metal properties (FLC) and the forming conditions (radii, lubrication, beads, blank size) will change the FLD, potentially affecting the conclusions.

 

Key Points

    • Conventional Forming Limit Curves characterize necking failure only. Fractures at cut edges and tight bends may occur at strains lower than that suggested by the Forming Limit Curve.
    • Differences in determination and interpretation of FLCs exist in different regions of the world. 
    • This system of FLCs commonly used for low strength and conventional HSLA is generally applicable to experimental FLCs obtained for DP steels for global formability.
    • The left side of the FLC (negative minor strains) is in good agreement with experimental data for DP and TRIP steels. The left side depicts a constant thinning strain as a forming limit.
    • Determination of FLCs for TRIP, MS, TWIP, and other special steels typically requires an experimental approach, since conventional simple equations do not accurately reflect the forming limits for these advanced microstructures.

 

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