1stGen AHSS, AHSS, Steel Grades
Dual Phase (DP) steels have a microstructure consisting of a ferritic matrix with martensitic islands as a hard second phase, shown schematically in Figure 1. The soft ferrite phase is generally continuous, giving these steels excellent ductility. When these steels deform, strain is concentrated in the lower-strength ferrite phase surrounding the islands of martensite, creating the unique high initial work-hardening rate (n-value) exhibited by these steels. Figure 2 is a micrograph showing the ferrite and martensite constituents.
Figure 1: Schematic of a Dual Phase steel microstructure showing islands of martensite in a matrix of ferrite.
Figure 2: Micrograph of Dual Phase Steel
Hot rolled DP steels do not have the benefit of an annealing cycle, so the dual phase microstructure must be achieved by controlled cooling from the austenite phase after exiting the hot strip mill finishing stands and before coiling. This typically requires a more highly alloyed chemistry than cold rolled DP steels require. Higher alloying is generally associated with a change in welding practices.
Continuously annealed cold-rolled and hot-dip coated Dual Phase steels are produced by controlled cooling from the two-phase ferrite plus austenite (α + γ) region to transform some austenite to ferrite before a rapid cooling transforms the remaining austenite to martensite. Due to the production process, small amounts of other phases (bainite and retained austenite) may be present.
Higher strength dual phase steels are typically achieved by increasing the martensite volume fraction. Depending on the composition and process route, steels requiring enhanced capability to resist cracking on a stretched edge (as typically measured by hole expansion capacity) can have a microstructure containing significant quantities of bainite.
The work hardening rate plus excellent elongation creates DP steels with much higher ultimate tensile strengths than conventional steels of similar yield strength. Figure 3 compares the engineering stress-strain curve for HSLA steel to a DP steel curve of similar yield strength. The DP steel exhibits higher initial work hardening rate, higher ultimate tensile strength, and lower YS/TS ratio than the HSLA with comparable yield strength. Additional engineering and true stress-strain curves for DP steel grades are presented in Figures 4 and 5.
Figure 3: A comparison of stress strain curves for mild steel, HSLA 350/450, and DP 350/600K-1
Figure 4: Engineering stress-strain curves for a series of DP steel grades.S-5, V-1 Sheet thicknesses: DP 250/450 and DP 500/800 = 1.0mm. All other steels were 1.8-2.0mm.
Figure 5: True stress-strain curves for a series of DP steel grades.S-5, V-1 Sheet thicknesses: DP 250/450 and DP 500/800 = 1.0mm. All other steels were 1.8-2.0mm.
DP and other AHSS also have a bake hardening effect that is an important benefit compared to conventional higher strength steels. The extent of the bake hardening effect in AHSS depends on an adequate amount of forming strain for the specific chemistry and thermal history of the steel.
In DP steels, carbon enables the formation of martensite at practical cooling rates by increasing the hardenability of the steel. Manganese, chromium, molybdenum, vanadium, and nickel, added individually or in combination, also help increase hardenability. Carbon also strengthens the martensite as a ferrite solute strengthener, as do silicon and phosphorus. These additions are carefully balanced, not only to produce unique mechanical properties, but also to maintain the generally good resistance spot welding capability. However, when welding the higher strength grades (DP 700/1000 and above) to themselves, the spot weldability may require adjustments to the welding practice.
Examples of current production grades of DP steels and typical automotive applications include:
| DP 300/500 |
Roof outer, door outer, body side outer, package tray, floor panel |
| DP 350/600 |
Floor panel, hood outer, body side outer, cowl, fender, floor reinforcements |
| DP 500/800 |
Body side inner, quarter panel inner, rear rails, rear shock reinforcements |
| DP 600/980 |
Safety cage components (B-pillar, floor panel tunnel, engine cradle, front sub-frame package tray, shotgun, seat) |
| DP 700/1000 |
Roof rails |
| DP 800/1180 |
B-Pillar upper |
Some of the specifications describing uncoated cold rolled 1st Generation dual phase (DP) steel are included below, with the grades typically listed in order of increasing minimum tensile strength and ductility. Different specifications may exist which describe hot or cold rolled, uncoated or coated, or steels of different strengths. Many automakers have proprietary specifications which encompass their requirements.
- ASTM A1088, with the terms Dual phase (DP) steel Grades 440T/250Y, 490T/290Y, 590T/340Y, 780T/420Y, and 980T/550YA-22
- EN 10338, with the terms HCT450X, HCT490X, HCT590X, HCT780X, HCT980X, HCT980XG, and HCT1180XD-6
- JIS G3135, with the terms SPFC490Y, SPFC540Y, SPFC590Y, SPFC780Y and SPFC980YJ-3
- JFS A2001, with the terms JSC590Y, JSC780Y, JSC980Y, JSC980YL, JSC980YH, JSC1180Y, JSC1180YL, and JSC1180YHJ-23
- VDA 239-100, with the terms CR290Y490T-DP, CR330Y590T-DP, CR440Y780T-DP, CR590Y980T-DP, and CR700Y980T-DPV-3
- SAE J2745, with terms Dual Phase (DP) 440T/250Y, 490T/290Y, 590T/340Y, 6907/550Y, 780T/420Y, and 980T/550YS-18
1stGen AHSS, 3rdGen AHSS, AHSS, Steel Grades
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The microstructure of Transformation Induced Plasticity (TRIP) steels contains a matrix of ferrite, with retained austenite, martensite, and bainite present in varying amounts. Production of TRIP steels typically requires the use of an isothermal hold at an intermediate temperature, which produces some bainite. Higher silicon and carbon content of TRIP steels result in significant volume fractions of retained austenite in the final microstructure. Figure 1 shows a schematic of TRIP steel microstructure, with Figure 2 showing a micrograph of an actual sample of TRIP steel. Figure 3 compares the engineering stress-strain curve for HSLA steel to a TRIP steel curve of similar yield strength.
Figure 1: Schematic of a TRIP steel microstructure showing a matrix of ferrite, with martensite, bainite and retained austenite as the additional phases.
Figure 2: Micrograph of Transformation Induced Plasticity steel.
Figure 3: A comparison of stress strain curves for mild steel, HSLA 350/450, and TRIP 350/600.K-1
During deformation, the dispersion of hard second phases in soft ferrite creates a high work hardening rate, as observed in the DP steels. However, in TRIP steels the retained austenite also progressively transforms to martensite with increasing strain, thereby increasing the work hardening rate at higher strain levels. This is known as the TRIP Effect. This is illustrated in Figure 4, which compares the engineering stress-strain behavior of HSLA, DP and TRIP steels of nominally the same yield strength. The TRIP steel has a lower initial work hardening rate than the DP steel, but the hardening rate persists at higher strains where work hardening of the DP begins to diminish. Additional engineering and true stress-strain curves for TRIP steel grades are shown in Figure 5.
Figure 4: TRIP 350/600 with a greater total elongation than DP 350/600 and HSLA 350/450. K-1
Figure 5: Engineering stress-strain (left graphic) and true stress-strain (right graphic) curves for a series of TRIP steel grades. Sheet thickness: TRIP 350/600 = 1.2mm, TRIP 450/700 = 1.5mm, TRIP 500/750 = 2.0mm, and Mild Steel = approx. 1.9mm. V-1
The strain hardening response of TRIP steels are substantially higher than for conventional HSS, resulting in significantly improved formability in stretch deformation. This response is indicated by a comparison of the n-value for the grades. The improvement in stretch formability is particularly useful when designers take advantage of the improved strain hardening response to design a part utilizing the as-formed mechanical properties. High n-value persists to higher strains in TRIP steels, providing a slight advantage over DP in the most severe stretch forming applications.
Austenite is a higher temperature phase and is not stable at room temperature under equilibrium conditions. Along with a specific thermal cycle, carbon content greater than that used in DP steels are needed in TRIP steels to promote room-temperature stabilization of austenite. Retained austenite is the term given to the austenitic phase that is stable at room temperature.
Higher contents of silicon and/or aluminum accelerate the ferrite/bainite formation. These elements assist in maintaining the necessary carbon content within the retained austenite. Suppressing the carbide precipitation during bainitic transformation appears to be crucial for TRIP steels. Silicon and aluminum are used to avoid carbide precipitation in the bainite region.
The carbon level of the TRIP alloy alters the strain level at which the TRIP Effect occurs. The strain level at which retained austenite begins to transform to martensite is controlled by adjusting the carbon content. At lower carbon levels, retained austenite begins to transform almost immediately upon deformation, increasing the work hardening rate and formability during the stamping process. At higher carbon contents, retained austenite is more stable and begins to transform only at strain levels beyond those produced during forming. At these carbon levels, retained austenite transforms to martensite during subsequent deformation, such as a crash event.
TRIP steels therefore can be engineered to provide excellent formability for manufacturing complex AHSS parts or to exhibit high strain hardening during crash deformation resulting in excellent crash energy absorption.
The additional alloying requirements of TRIP steels degrade their resistance spot-welding behavior. This can be addressed through weld cycle modification, such as the use of pulsating welding or dilution welding. Table 1 provides a list of current production grades of TRIP steels and example automotive applications:
Table 1: Current Production Grades Of TRIP Steels And Example Automotive Applications.
Some of the specifications describing uncoated cold rolled 1st Generation transformation induced plasticity (TRIP) steel are included below, with the grades typically listed in order of increasing minimum tensile strength and ductility. Different specifications may exist which describe hot or cold rolled, uncoated or coated, or steels of different strengths. Many automakers have proprietary specifications which encompass their requirements.
• ASTM A1088, with the terms Transformation induced plasticity (TRIP) steel Grades 690T/410Y and 780T/440YA-22
• JFS A2001, with the terms JSC590T and JSC780TJ-23
• EN 10338, with the terms HCT690T and HCT780TD-18
• VDA 239-100, with the terms CR400Y690T-TR and CR450Y780T-TRV-3
• SAE J2745, with terms Transformation Induced Plasticity (TRIP) 590T/380Y, 690T/400Y, and 780T/420YS-18
Transformation Induced Plasticity Effect
Austenite is not stable at room temperature under equilibrium conditions. An austenitic microstructure is retained at room temperature with the combined use of a specific chemistry and controlled thermal cycle. Deformation from sheet forming provides the necessary energy to allow the crystallographic structure to change from austenite to martensite. There is insufficient time and temperature for substantial diffusion of carbon to occur from carbon-rich austenite, which results in a high-carbon (high strength) martensite after transformation. Transformation to high strength martensite continues as deformation increases, as long as retained austenite is still available to be transformed.
Alloys capable of the TRIP effect are characterized by a high ductility – high strength combination. Such alloys include 1st Gen AHSS TRIP steels, as well as several 3rd Gen AHSS grades like TRIP-Assisted Bainitic Ferrite, Carbide Free Bainite, and Quench & Partition Steels.
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![Complex Phase]()
1stGen AHSS, AHSS, Steel Grades
Complex Phase (CP) steels combine high strength with relatively high ductility. The microstructure of CP steels contains small amounts of martensite, retained austenite and pearlite within a ferrite/bainite matrix. A thermal cycle that retards recrystallization and promotes Titanium (Ti), Vanadium (V), or Niobium (Nb) carbo-nitrides precipitation results in extreme grain refinement. Minimizing retained austenite helps improve local formability, since forming steels with retained austenite induces the TRIP effect producing hard martensite.F-11
The balance of phases, and therefore the properties, results from the thermal cycle, which itself is a function of whether the product is hot rolled, cold rolled, or produced using a hot dip process. Citation P-18 indicates that galvannealed CP steels are characterized by low yield value and high ductility, whereas cold rolled CP steels are characterized by high yield value and good bendability. Typically these approaches require different melt chemistry, potentially resulting in different welding behavior.
CP steel microstructure is shown schematically in Figure 1, with the grain structure for hot rolled CP 800/1000 shown in Figure 2. The engineering stress-strain curves for mild steel, HSLA steel, and CP 1000/1200 steel are compared in Figure 3.
Figure 1: Schematic of a complex phase steel microstructure showing martensite and retained austenite in a ferrite-bainite matrix.
Figure 2: Micrograph of complex phase steel, HR800Y980T-CP.C-14
Figure 3: A comparison of stress strain curves for mild steel, HSLA 350/450, and CP 1000/1200.
DP and TRIP steels do not rely on precipitation hardening for strengthening, and as a result, the ferrite in these steels is relatively soft and ductile. In CP steels, carbo-nitride precipitation increases the ferrite strength. For this reason, CP steels show significantly higher yield strengths than DP steels at equal tensile strengths of 800 MPa and greater. Engineering and true stress-strain curves for CP steel grades are shown in Figure 4.
Figure 4: Engineering stress-strain (left graphic) and true stress-strain (right graphic) curves for a series of CP steel grades. Sheet thickness: CP650/850 = 1.5mm, CP 800/1000 = 0.8mm, CP 1000/1200 = 1.0mm, and Mild Steel = approx. 1.9mm.V-1
Examples of typical automotive applications benefitting from these high strength steels with good local formability include frame rails, frame rail and pillar reinforcements, transverse beams, fender and bumper beams, rocker panels, and tunnel stiffeners.
Some of the specifications describing uncoated cold rolled 1st Generation complex phase (CP) steel are included below, with the grades typically listed in order of increasing minimum tensile strength and ductility. Different specifications may exist which describe hot or cold rolled, uncoated or coated, or steels of different strengths. Many automakers have proprietary specifications which encompass their requirements.
- ASTM A1088, with the terms Complex phase (CP) steel Grades 600T/350Y, 780T/500Y, and 980T/700Y A-22
- EN 10338, with the terms HCT600C, HCT780C, and HCT980C D-18
- VDA239-100, with the terms CR570Y780T-CP, CR780Y980T-CP, and CR900Y1180T-CPV-3
Joining, Laser Welding
Optimizing weld morphology and mechanical properties of
laser welded Al-Si coated 22MnB5 by surface application of
colloidal graphite
Researchers at University of Waterloo discovered the microstructural effects of adding colloidal graphite to Al-Si coated 22MnB5 Press Hardened Steel.K-51 Laser welds were made on 1.5 mm thick Al-Si coated 22MnB5 PHS perpendicular to the rolling direction. Pure colloidal graphite suspended in isopropanol base was applied to the area being welded and the resulting graphite coating after evaporation ranged from 5 µm to 130 μm for testing. Parameters used for the weld are: 4kW power, 6m/min welding speed, beam diameter of 0.3 mm, and laser defocus of 6mm. Samples were then hot stamped by heating for 6 min to 930 ᵒC in a furnace and then water quenched at a cooling rate greater than 30 ᵒC/s.
Al-Si coating is excellent at preventing oxidation and decarburization of high strength steel at elevated temperatures. However, during welding there is diffusion of Al into the fusion zone which stabilizes ferrite at elevated temperature reducing the strength of the welded joint. Colloidal graphite coating decreases the Al content and increases C content of the fusion zone. As shown in Figure 1, The mechanism for reduction in Al content is due the graphite coating acting as an insulator to the Al-Si coating which then causes an ejection of the molten Al-Si coating from the surface. Figure 2 displays a proportional reduction of Al in the fusion zone with increasing graphite coating thickness up to 40 μm where after the reduction in Al is minimal. This is attributed to the initial reduction of Al being caused by the ejection of the molten Al-Si from underneath the graphite coating. Graphite coating greater than 40 µm does not aid in additional ejection of Al-Si and the Al-Si coating already diluted in the weld pool will not be removed.
Figure 1: Al-Si ejection mechanism.K-51
Figure 2: Al and C content in weld with increasing graphite thickness.K-51
Summary
Ferrite concentration in the fusion zone was reduced from approx. 40% with no graphite coating to approx. 2% with 130 μm graphite coating thickness (Figure 3). The increase in C content and reduction in Al content resulted in an increase in austenite being stabilized at elevated temperature rather than ferrite and therefore a larger percentage of martensite results after hot stamping. The average fusion zone hardness increased from 320 HV with no coating to 540 HV with 130 μm coating thickness (Figure 4). The weld strength of the sample with no graphite coating was 1249±15MPa whereas the weld strength with a coating of 130 µm was 1561±7MPa which matches the base metal (Figure 5). With an increase in graphite coating thickness there is an increase in weld strength that can eventually match the base metal strength.
Figure 3: Ferrite concentration in weld.K-51
Figure 4: Fusion Zone Hardness vs. Graphite Thickness.K-51
Figure 5: Weld strength vs. Graphite Thickness.K-51
Microstructural Components
Steel grades are engineered to achieve specific properties and characteristics by the manipulation of mill processing parameters to achieve a targeted balance of microstructural components. Among the tools available to the steelmaker are alloy composition, rolling and processing temperatures, and cooling profile.
If steel is slowly cooled, only two components exist at room temperature: ferrite (abbreviated by the Greek letter α) and cementite (iron carbide, Fe3C). Alternating layers of ferrite and cementite appear under a microscope in a pattern similar to Mother-of-Pearl, leading to the term pearlite.
A steel alloy having approximately 0.80% carbon will contain only pearlite in the microstructure. Lower carbon levels create an alloy that combines ferrite and pearlite. Ferrite-pearlite microstructures form the basis of many C-Mn steels and some of the initial HSLA steels. At a given strength level, pearlite limits sheet formability.
At carbon levels below 0.008% or 80 ppm, only ferrite exists. Ferrite is low strength but very ductile, and is the microstructural phase in ultra-low carbon steels.
Additional phases are formed when the cooling profile can be changed. Some modern annealing furnaces are capable of controlling the cooling rate as well as holding at specific temperatures. This ability is a key facilitator in the production of most Advanced High Strength Steels. In addition to ferrite and pearlite, microstructural phases of bainite, austenite, and martensite can be produced, depending on the chemistry and the thermal cycle profile including quench rate and hold temperature.
Bainite is a phase that is associated with enhanced sheared edge ductility. Accelerated cooling in the hot mill run out table allows for the production of Ferrite-Bainite steels.
Austenite is not stable at room temperature under equilibrium conditions. An austenitic microstructure is retained at room temperature with the use of a combined chemistry and controlled thermal cycle. Deforming retained austenite is responsible for the TRIP effect.
Martensite is a very high strength phase, but has limited toughness. Steels with both ferrite and martensite in the microstructure are known as dual phase steels. A structure of 100% martensite can be produced directly at those sheet mills having equipment capable of achieving a minimum critical cooling rate. The ductility of this product is not sufficiently high for most stamping operations. However, sheet martensite is well suited for properly designed roll forming applications.
Martensite is the microstructural component of processed Press Hardening Steels. An elevated temperature and a more formable microstructure exist at the time of complex forming of these grades. Rapid cooling while the part is under full press load converts the microstructure to the high strength martensite.
