Joining, Laser Welding
Optimizing weld morphology and mechanical properties of
laser welded Al-Si coated 22MnB5 by surface application of
colloidal graphite
Researchers at University of Waterloo discovered the microstructural effects of adding colloidal graphite to Al-Si coated 22MnB5 Press Hardened Steel.K-51 Laser welds were made on 1.5 mm thick Al-Si coated 22MnB5 PHS perpendicular to the rolling direction. Pure colloidal graphite suspended in isopropanol base was applied to the area being welded and the resulting graphite coating after evaporation ranged from 5 µm to 130 μm for testing. Parameters used for the weld are: 4kW power, 6m/min welding speed, beam diameter of 0.3 mm, and laser defocus of 6mm. Samples were then hot stamped by heating for 6 min to 930 ᵒC in a furnace and then water quenched at a cooling rate greater than 30 ᵒC/s.
Al-Si coating is excellent at preventing oxidation and decarburization of high strength steel at elevated temperatures. However, during welding there is diffusion of Al into the fusion zone which stabilizes ferrite at elevated temperature reducing the strength of the welded joint. Colloidal graphite coating decreases the Al content and increases C content of the fusion zone. As shown in Figure 1, The mechanism for reduction in Al content is due the graphite coating acting as an insulator to the Al-Si coating which then causes an ejection of the molten Al-Si coating from the surface. Figure 2 displays a proportional reduction of Al in the fusion zone with increasing graphite coating thickness up to 40 μm where after the reduction in Al is minimal. This is attributed to the initial reduction of Al being caused by the ejection of the molten Al-Si from underneath the graphite coating. Graphite coating greater than 40 µm does not aid in additional ejection of Al-Si and the Al-Si coating already diluted in the weld pool will not be removed.
Figure 1: Al-Si ejection mechanism.K-51
Figure 2: Al and C content in weld with increasing graphite thickness.K-51
Summary
Ferrite concentration in the fusion zone was reduced from approx. 40% with no graphite coating to approx. 2% with 130 μm graphite coating thickness (Figure 3). The increase in C content and reduction in Al content resulted in an increase in austenite being stabilized at elevated temperature rather than ferrite and therefore a larger percentage of martensite results after hot stamping. The average fusion zone hardness increased from 320 HV with no coating to 540 HV with 130 μm coating thickness (Figure 4). The weld strength of the sample with no graphite coating was 1249±15MPa whereas the weld strength with a coating of 130 µm was 1561±7MPa which matches the base metal (Figure 5). With an increase in graphite coating thickness there is an increase in weld strength that can eventually match the base metal strength.
Figure 3: Ferrite concentration in weld.K-51
Figure 4: Fusion Zone Hardness vs. Graphite Thickness.K-51
Figure 5: Weld strength vs. Graphite Thickness.K-51
Joining, Laser Welding
In this study by Shanghai Jiao Tong University and General Motors Company on liquid metal Embrittlement (LME)Z-11, hot dipped 1.2mm galvanized QP980 steel sheets with a 6 micron thick zinc rich coating on top of a 2 micron thick transition zone to the base metal were used. The laser welder is tilted 5º ahead of weld pool to avoid back reflection. The welding velocity was varied from 4-6 m/min and laser power from 4-6.5 kW. Referencing Table 1, Schedules #1–4 were intended to investigate effects of laser power on LME cracks using 6 m/min. schedules #4–6 varied velocity with the laser power staying constant at 4.5 kW. In addition, schedules #6 and #7 varied laser power at a relatively lower welding velocity of 4 m/min.
Table 1: Process Parameters.Z-11
Full penetration welds did not result in cracking while partial penetration welds with lower energy density did. The lowest energy density welds resulted in no cracking but the penetration was barely beyond the faying surface. Cracks resembles an inverse “Y” where the cracks initiated at the faying surface and propagated along the direction of solidification towards the weld centerline. Cracks at notch root were wider than centerline crack indicating grain boundary separation. The fracture method is characteristic of quasi-cleavage indicating that the grain boundaries were embrittled by Fe-Zn intermetallics. Crack initiation at the faying surface can be explained by the residual stresses that form highest at the faying surface during cooling. This stress concentration is eliminated with full penetration weld pass as well as in wide and shallow passes as seen in Figure 1.
Figure 1: Von Mises Stress Distribution.Z-11
Because the process of laser welding is so short, the vaporized zinc and intermetallics do not have time to outgas completely. The liquid zinc diffuses along the austenite grain boundaries and stabilize ferrite given ferrite has a higher solubility of Zn compared to austenite. The remaining liquid Zn reacts with the ferrite to form the solid Γ-Fe3Zn10 which is a hard brittle intermetallic that can easily induce cracking. Another peritectic reaction occurs with Γ-Fe3Zn10 and liquid zinc forming another brittle intermetallic δ-FeZn10. The stabilized ferrite and intermetallics occur before austenite transform to martensite and remains even after this reaction occurs.
The formation of the intermetallics between the grain boundaries decreases ductility and with the combination of the high residual stress and stress concentration at the faying surface, the crack initiates and propagates. The cracking follows the grain growth to the center of the weld. Liquid Zn accumulates at the center of the weld and results in Fe-Zn intermetallics with low ductility that can eventually propagate cracking that occurs at the edge of the weld. Welds that result in a smaller cross-sectional area on the faying surface benefit from the reduction in vaporized Zn that cannot be outgassed while full penetration welds with keyhole mode can allow Zn to out gas from both the top and bottom of the weld as well as increased nugget size decreasing the Zn concentration to where brittle Fe-Zn phases do not form. Full penetration welds are recommended to reduce residual stress as well as allow sufficient outgassing of vaporized Zn in the weld pool.
Figure 2: LME illustration.Z-11
Figure 3: Zn diffusion.Z-11
Summary
LME cracks initiated at the weld notch root on the faying surface and propagated towards the center of the weld along the direction of columnar growth. Brittle intermetallic help induce cracking in the weld metal in addition to restraint from the weld joint. Full penetration welds were found to reduce Zn content from the weld in addition to reducing restraint as compared to partial penetration welds. The full penetration weld allowed for zinc to be outgassed from the weld on both sides reducing the Zn content in the weld to an acceptable level. Full penetration welds also reduced the residual stresses that formed during partial penetration welds due to the restraint on the root side of the weld.
Joining, Laser Welding, Press Hardened Steels
This studyR-25, conducted by the Centre for Advanced Materials Joining, Department of Mechanical & Mechatronics Engineering, University of Waterloo, and ArcelorMittal Global Research, utilized 2mm thick 22MnB5 steel with three different coating thicknesses, given in Table 1. The fiber laser welder used 0.3mm core diameter, 0.6mm spot size, and 200mm beam focal length. The trials were done with a 25° head angle with no shielding gas but high pressure air was applied to protect optics. Welding passes were performed using 3-6kW power increasing by 1 kW and 8-22m/min welding speed increasing by 4m/min. Compared to the base metal composition of mostly ferrite with colonies of pearlite, laser welding created complete martensitic composition in the FZ and fully austenized HAZ while the ICHAZ contained martensite in the intergranular regions where austenization occurred.
Table 1: Galvanneal Coatings.R-25
Figure 1: Base metal microstructure(P=pearlite, F=ferrite, Γ=Fe3Zn10, Γ1=Fe5Zn21 and δ=FeZn10).R-25
Figure 2: Welded microstructure — (a) overall view, (b) HAZ, (c) ICHAZ at low and (d) high magnifications, (e) UCHAZ (f) FZ, and (g) coarse-lath martensitic structure (where M; martensite, P: pearlite, F: ferrite).R-25
Given the lower boiling temperature of Zn at 900 °C as compared to Fe, the interaction of the laser with the Zn plasma that forms upon welding affects energy deliverance and depth of penetration. Lower coating weight of (100 g/m2) resulted in a larger process window as compared to (140 g/m2). Increased coating weight will reduce process window and need higher power and lower speeds in order to achieved proper penetration as shown in Figure 3 and Figure 4. Depth of penetration due to varying welding parameters was developed:
d=(H-8.6+0.08C)/(0.09C-4.8)
[d= depth of penetration(mm), H= heat input per unit thickness(J/mm2), C= coating weight(g/m2)]
Given the reduction in power deliverance, with an increase in coating weight there will be an expected drop in FZ and HAZ width. Regardless of the coating thickness, the HAZ maintained its hardness between BM and FZ. No direct correlation between coating thickness and YS, UTS, and elongation to fracture levels were observed. This is mainly due to the failure location being in the BM.
Figure 3: Process map of the welding window at coating weight of (a) 100 g/m2, (b) 120 g/m2, and (c) 140 g/m2.R-25
Figure 4: Heat input per unit thickness vs depth of penetration.R-25
Joining Dissimilar Materials, Laser Welding
Given the use of many different metals in the Body in White construction, it is important to understand the effects of dissimilar welding AHSS. Researchers at Indian Institute of Technology Madras in Chennai, India and Centre of Laser Processing of Materials in Hyderabad, India developed tests to study the resulting microstructure from laser welding 2.5 mm thick DP600 steel to 3 mm thick AA6061 aluminium alloy using a laser beam diameter of 1.5 mm.I-1 They discovered a softening in the steel HAZ due to a tempering effect and an increase in hardness in the aluminum HAZ due to the presence of aluminium intermetallic phases present. Maximum shear strength was observed when the thickness of intermetallics was reduced to 8-11 microns. They concluded that best quality welds were made under power densities and interaction times of 1.98kW/mm2, 0.15s and 2.26 kW/mm2, 0.187s.
The laser power was varied from 3 kW to 4.5 kW and the scanning speed of 8 mm/s, 10 mm/s, and 12 mm/s. Power density and interaction time were two parameters they used to compare trials where:
| Power density (Pd) = |
|
and
| interaction time (It) = |
 |
The resulting welding parameters are shown in Table 1 below. Figure 1 shows the microstructure of the fusion boundary and HAZ on the DP600 side of the welded joint. Figure 2 shows the microstructure of the weld interface on the AA 6061 side. Figure 3 displays the hardness data with (a) representing 3.5 kW and 10 mm/s, (b) representing 3.5 kW and 8 mm/s, and (c) representing 4 kW and 8 mm/s. Figure 4 represents the Shear Stress-Strain of the welds given different IMC thickness.
Table 1: Welding Parameters.I-1
Figure 1: Weld Metal, DP 600 Base Metal and HAZ microstructure.I-1
Figure 2: Fe-Al interface microstructure.I-1
Figure 3: Microhardness Plot.I-1
Figure 4: Load vs. Displacement.I-1
Arc Welding, Joining
Quenching and partitioning (QP) steels are one of several third generation advanced high strength steel formed by controlled martensite phase fractions and retained austenite. Researchers from the University of Shanghai Jiao Tong tested the effect of HAZ softening in a QP1180 lap joint with the GMAW cold metal transfer (CMT) process.W-1 The steel was welded with ER130s electrode. The fusion zone consisted of chiefly acicular ferrite. The supercritical zone consists of martensite, which is harder than the base metal. There is a drop in hardness (100 HV) in the subcritical zone, and there is a noted lack of retained austenite present in the microstructure. Precipitates are also present in the subcritical zone. The intercritical HAZ only experiences mild softening; where fresh martensite has formed. The softening in the subcritical HAZ presents room for failure that must be accounted for when planning welding using CMT.
Figure 1 shows the different microstructures in detail throughout the weld and the base metal. In the softening zone shown in Figure 2 correlates to the tempered sorbite region in Figure 1 (part f). The hardness maps shows that the fusion zone is approximately as hard as the base metal, with the supercritical HAZ having the highest hardness values before rapidly softening in the intercritical and subcritical HAZ zones. The softened region must be accounted for in designing CMT or other high heat input welded components.
Figure 1: a) Base metal with retained austenite between martensite lathes, b) fusion zone with acicular ferrite and ferrite, c) coarse martensite grains in supercritical HAZ, d) fine martensite grains and ferrite in supercritical HAZ, e) intercritical HAZ with fresh martensite and untransformed martensite, f) softest region in subcritical HAZ; shows tempered sorbite, g)zoomed in region of subcritical zone with precipitates, h) subcritical HAZ with 350-360HV hardness, i) hardness with 380-390HV.W-1
Figure 2: a) macrostructure of the CMT-welded QP1180 joint, b) hardness chart through joint, c) hardness map in upper sheet, d) hardness map in lower sheet. 1) fusion zone, 2) supercritical HAZ, 3) intercritical HAZ, 4) subcritical HAZ, BM = base metal.W-1
Arc Welding, Joining
A common issue when welding Advanced High-Strength Steels (AHSS) is with protective coatings causing weld defects. A group of researchers at the NMAM Institute of Technology and Dong-Eui University studied common issues with gas metal arc welding (GMAW) in the cold metal transfer (CMT) mode on a zinc-coated steel.V-2 The study used infrared thermography to observe the welds as they were created, helping to get detailed observations on some defects appearing in real time. With GMAW in CMT mode, the prevailing defect with welding a zinc-coated steel was porosity from metal vapors escaping through the weld. This issue could be addressed by adjusting the heat input and travel speed to provide more time for metal gases to escape.
In Figure 1, it shows that with a higher heat input, more heat is in the weld puddle. In low and medium heat inputs, the puddle is above melting temperature, but not as high as the high heat input. Figure 2 shows that the low heat input also has the fastest solidification rate, and the high heat input has the slowest solidification rate. Figure 3 shows where the zinc vapors from the molten coating evaporate through the weld. In the left picture, at low heat input, the nucleation is contained inside of the weld, and the fusion zone would collect in the fusion zone. In the middle picture, at medium heat input, the zinc vapors bubble out just as the metal starts to solidify. In the right picture, at high heat input, the zinc bubbles out in the weld puddle while it is still molten.
Figure 1: Infrared Thermography of Weld Bead.V-2
Figure 2: Variation of temperature during CMT for High, Medium, and Low Heat Input.V-2
Figure 3: Variation of Zinc Porosity Position vs Low, Medium, and High Heat Input.V-2
These factors combined indicate several factors that influence zinc porosity in GMAW CMT weldments. The researchers concluded that at low heat inputs, the zinc collects in the fusion zone. At medium heat inputs, the solidification rate and temperature gradient through the weld puddle traps the zinc in the fusion zone but also allows some to bubble out through the weld puddle. This caused the worst material properties of the three weldments for the researchers. At high heat inputs, the zinc bubbles out through the weld puddle, before solidification occurs. This condition is optimal, to reduce porosity with zinc metal vapors, the heat input should be increased so that the weldment temperature increases and solidification rate decreases.
