PHS Production Methods

PHS Production Methods

In its simplest explanation hot stamping consists of five operations: (1) blanking (or cutting-to-length), (2) forming, (3) heating, (4) cooling (quenching) and (5) trimming/piercing. Each process route listed below has a distinct order or type of these operations.

In most sources, hot stamping is explained with only two processes: Direct hot stamping (also known as Press Hardening) and indirect hot stamping (also known as Form Hardening). While this used to be accurate, there are currently at least 10 processes for part manufacturing:

  1. Direct Process (Blanking > Heating > Forming > Quenching > Trimming)
  2. Indirect Process (Blanking > Forming & Trimming > Heating > Quenching > Trimming)
  3. Hybrid Process (Blanking > 1st Forming > Heating > 2nd Forming > Quenching > Trimming)
  4. Pre-cooled Direct Process (Blanking > Heating > Pre-cooling > Forming > Quenching > Trimming)
  5. Multi-Step Process (Blanking > Heating > Pre-cooling > Forming and Trimming > Air Quenching)
  6. Form Fixture Hardening (Roll Forming > Cut-to-length > Heating > Bending forming > Quenching > Trimming / piercing)
  7. Roll Form PHS (Roll Forming > Heating > Quenching > Cut-to-length > Trimming & piercing)
  8. Form Blow Hardening / Hot gas metal forming (Cut-to-length tube or roll formed / welded profile > Heating > Pressure forming > Quenching > Piercing)
  9. 3DQ (Cut-to-length tube > Local induction heating > 3-D Bending > Direct Water Quenching > Piercing)
  10. STAF (Cut-to-length tube > Cold preforming > Heating > Pressure Forming > Quenching > Piercing)

The video below explains some of these processes and how they are employed at Gestamp Automoción. Here, Paul Belanger, Director of Gestamp’s North American R&D Center, was interviewed by Kate Bachman, the Editor of STAMPING Journal®. Thanks are given to Paul and Kate, as well as FMA, Fabricators & Manufacturers Association®, for permission to reproduce this video.

 

 

Direct Process

The most common process route in hot stamping is still the direct process (also known as press hardening).D-20 Here, previously cut blanks are heated typically in a roller hearth or a multi-chamber furnace to over 900 °C to create a fully austenitic microstructure. Depending on the material handling system, transfer from the furnace to the press may take up 6 to 10 seconds.B-14  During this time, the blank may cool down to 700 °C.G-24 Forming is done immediately after the blanks are transferred on the die, and should be completed before the blank cools below 420 °C.G-24, K-18 The blanks are formed in hot condition (state  in Figure 1), and quenched in the same die to achieve the required properties. For 22MnB5 steel, if the quenching rate is over 27 °C/s, the part will transform to almost 100% martensite. For productivity purposes, higher cooling rates are often realized.K-18 Typical cycle times for a direct process with the 22MnB5 chemistry could be between 10 and 20 seconds, depending on the thickness.B-14 Global R&D efforts target improvements in cycle time.

The process is typically used for bare/uncoated steels or AlSi coated steels. Zn coated blanks are not suitable for direct process, as pure Zn melts around 420 °C and GA (Zn-Fe) coatings around 530-780 °C. (see Figure 3)G-25 If forming is done with liquid Zn over the blank, microcracks may fill with Zn and lower the fatigue strength of the final part significantly.K-20 A recently developed alloy minimizes these concerns, as explained in the “Pre-cooled Direct Process” section below.

Figure 1: Summary of hot stamping processes. In direct process forming is done at state (1), in indirect process at (2) B-14

Figure 1: Summary of hot stamping processes. In direct process forming is done at state , in indirect process at B-14

 

Typical Al-Si coatings prevent scale formation and decarburization at elevated temperatures. The aluminum-rich coating contains 7% to 11 wt.% Si, and acts as a barrier to offer corrosion resistance during service.F-14 In automotive industry, typical coating weights are AS150 (75 g/m2 coating on each side) or AS80 (40 g/m2 coating on each side).A-51 Refer to our page on Al-Si coatings for more details.

When using uncoated blanks, controlled atmosphere in the furnace helps avoid excessive decarburization and scale formation. Surface scale locally changes the critical cooling rate, alters the metal flow and friction, and leads to premature tool wear. Without a controlled atmosphere, a surface conditioning step like shot blasting may be required after forming to remove the scale.A-52  Varnish coatings may also be used with direct hot stamping.

Formed parts must be trimmed and pierced to final geometry. In the direct process, the most common trimming method is laser cutting. The capital expense and cycle times associated with laser trimming factor into overall part cost calculations. In most plants, for every hot stamping line, there are 3 to 5 laser trimming machines.B-14

The grades used with the direct process may be referred to as PHS950Y1500T-DS (Press Hardening Steel with minimum 950 MPa yield, minimum 1500 MPa tensile strength, for Direct [Hot] Stamping).

 

Indirect Process

(Blanking > Forming & Trimming > Heating > Quenching > Surface Conditioning)

Typically used for galvanized blanks, indirect hot stamping, also known as form hardening, starts by cold forming the part (at in Figure 1) in a transfer press or a tandem transfer line. The direct process is limited in that only one forming die can be used. However, the indirect process can accommodate multiple die stations, allowing for the production of more complicated geometries, even those with undercuts. The part has almost the final shape exiting the cold forming press, where piercings and trimming could also be completed. The formed parts are then heated in a special furnace and quenched in a second die set.B-14,K-21,F-15

BMW 7 Series (2008-2015, codenamed F01) was the first car to have Zn-coated indirect hot stamped steel in its body-in-white.P-20  Zn-based coatings are favored for their cathodic protection. Zn-coated blanks may develop a thin oxide layer during heating, even if a protective atmosphere is used in the furnace. This layer helps preventing evaporation of the Zn (pure Zn evaporates at 907 °C at 1 atm. pressure), but must be removed before welding and painting. To achieve this, sandblasting, shot blasting or dry-ice (CO2) blasting are typically used.F-14, F-15  The grades for indirect process may be referred to as PHS950Y1500T-IS (Press Hardening Steel with minimum 950 MPa yield, minimum 1500 MPa tensile strength, for Indirect [Hot] Stamping).

The indirect process cannot be applied to Al-Si coated blanks, as they have a hard but brittle intermetallic layer which would crack during cold deformation.F-14

 

Hybrid (2-Step) Process

(Blanking > 1st Forming > Heating > 2nd Forming > Quenching > Trimming > Surface Conditioning)

In this process, as summarized in Figure 2, some of the forming occurs at the cold stage [ in Figure 1]. The semi-formed part then is heated in the furnace, significantly deformed to a final shape [ in Figure 1] and subsequently quenched in the same die. This process had found greater use in Europe, especially for deep drawn parts such as transmission tunnels. To avoid scale formation in the furnace and hot forming, a special varnish-type coating is commonly used. The final part must be surface cleaned with a process like shot blasting before welding to remove the varnish coating.S-63  Since the early 2010s, the process has been replaced by the direct process of Al-Si-coated blanks.N-15

Figure 2: Summary of “hybrid process” where deformation is done both at cold and hot conditions.B-14

Figure 2: Summary of “hybrid process” where deformation is done both at cold and hot conditions.B-14

 

Pre-Cooled Direct Process

(Blanking > Heating > Pre-cooling > Forming > Quenching > Trimming > Surface conditioning)

A galvannealed (GA) coating primarily contains zinc and iron, and solidifies at temperatures between 530 °C and 782 °C, depending on the zinc content, as shown in Figure 3. Liquid Metal Embrittlement (LME) is not a concern if forming is done in the absence of liquid zinc.G-25  Hensen et al. conducted several studies heating galvannealed 22MnB5 blanks to 900 °C, but forming after a pre-cooling stage. As seen in Figure 4, the microcrack depth is significantly reduced when the forming starts at lower temperatures.H-26

Figure 3: Temperature limit to ensure absence of Zn-rich liquid (re-created after Citations G-25 and G-26)

Figure 3: Temperature limit to ensure absence of Zn-rich liquid (re-created after Citations G-25 and G-26)

 

Figure 4: Crack depth reduces significantly if the forming is done at lower temperature (re-created after Citation H-26)

Figure 4: Crack depth reduces significantly if the forming is done at lower temperature (re-created after Citation H-26)

 

In the pre-cooled direct process, the blank is heated above the austenitization temperature (approximately 870-900 °C), and kept in the furnace for a minimum soaking time of 45 seconds. Once the blank leaves the furnace, it is first pre-cooled to approximately 500 °C and then formed. Typical 22MnB5 cannot be formed at this temperature due to two reasons: (1) its formability would be reduced and (2) forming could not be completed before the start of martensite formation at approximately 420 °C).K-22, V-8

The development of a “conversion-delayed” hot stamping grade (see PHS Grades with approximately 1500 MPa TS), commonly known as 20MnB8, addresses these concerns. This steel has lower carbon (0.20%, as the number 20 in 20MnB8 implies), but higher Mn (8/4 = 2%). . This chemistry modification slows the kinetics of the phase transformation compared with 22MnB5 – the critical cooling rate of 20MnB8 is approximately 10 °C/s. This allows the part to be transferred from pre-cooling stage to the forming die.

In the pre-cooled direct process, first the blank is heated to over 870-900 °C and soaked for at least 45 seconds. Then the blank is transferred to “pre-cooling stage” in less than 10 seconds. Precooling must be done at a rate over 20 °C/s, until the blank is cooled to approximately 500 °C. Then the part is transferred from the pre-cooling device to the press in less than 7 seconds. The forming is done in one hit in a hydraulic or servo-mechanical press, which can dwell at the bottom. The cooling rate after pre-cooling is advised to be over 40 °C/s. The final part may have zinc oxides and surface cleaning is required.K-22, V-8 The grade may be referred to as PHS950Y1500T-PS (Press Hardening Steel with minimum 950 MPa yield, minimum 1500 MPa tensile strength, Pre-cooled and Stamped).

Recently, several researchers have shown that pre-cooling may be used for drawing deeper partsO-6 or to achieve better thickness distribution of the final part.G-24 Since formed parts are typically removed from the press at approximately 200 °C, a pre-cooled part may require shorter time to quench, thus increasing the parts per minute.G-24

Multi-Step Process

(Blanking > Heating > Pre-cooling > Forming and Trimming > Air Quenching)

22MnSiB9-5 (see PHS Grades with approximately 1500 MPa TS) is a new steel grade developed by Kobe SteelH-27 for a transfer press process, named as “multi-step”. This steel has higher Mn and Si content, compared to typical 22MnB5. As quenched, the material has similar mechanical properties with 22MnB5. As of 2020, there is at least one automotive part mass produced with this technology and is applied to a compact car in Germany.G-27 Although critical cooling rate is listed as 2.5 °C/s, even at a cooling rate of 1 °C/s, hardness over 450HV can be achieved.H-27 This critical cooling rate allows the material to be “air-hardenable” and thus, can handle a transfer press operation (hence the name multi-step) in a servo press. This material is available only with Zn coating and requires a pre-cooling step before the transfer press operation.B-15 The grade may be referred to as PHS950Y1500T-MS (Press Hardening Steel with minimum 950 MPa yield, minimum 1500 MPa tensile strength, for Multi-Step process).

 

Roll Form PHS

(Roll Forming > Heating > Quenching > Cut-to-length > Trimming & piercing)

Also known as inline hardening, this process is used to make profiles with constant cross sections and linear shapes. It is also possible to have closed profiles (tubes and similar) with this technology by adding a laser welding to the line (see Figure 5a). The process has been successfully used in many car bodies. Typical uses are: cross members, roof bows, side impact door beams, bumpers (with no sweep), front crash components and similar.G-28, H-28, F-16

Figure 5: Roll form PHS: (a) steps of the line [24], (b) photo of the induction heated area.G-28

Figure 5: Roll form PHS: (a) steps of the lineH-28, (b) photo of the induction heated area.G-28

The heating is typically done with induction heating, see Figure 5b. In one of the installations, the first induction coil operates at 25 kHz and the second at 200 kHz. The total heating power was approximately 700 kW and the line can run as fast as 6 m/s. It was found that if lubrication, speed and bending radius can be optimized, AlSi coated blanks could also be cold roll formed. However, they are not suitable for induction heating and may require a different process, such as form fixture hardening.K-23

Recently, voestalpine developed a Zn-coated steel for roll forming applications. This process also uses induction heating and water cooling. As the deformation is done at cold condition, the parts do not suffer from liquid metal embrittlement (LME).K-22

 

Form Fixture Hardening

(Roll Forming (or tube blank) > Cut-to-length > Heating > Bending & forming > Quenching > Trimming / Piercing)

The main difference between roll form PHS and form fixture hardening is the secondary “hot bending and forming” in the press. Here, cold roll formed profiles are cut-to-length and heated in a furnace. Heated profiles are then transferred to a press die, where sweep bending and/or further forming operations are completed. The parts are subsequently quenched in the same press die, similar to direct process. A typical line layout can be seen in Figure 6a. The secondary forming makes variable sections possible, as seen in Figure 6b. As the parts are cold roll formed and furnace heated, uncoated, Zn-coated and AlSi-coated (with precautions not to crack AlSi) blanks may be used in this process.H-28, K-23

Figure 6: Form fixture hardening: (a) schematic of a lineK-23, (b) bumper beam of Ford Mustang (2004-2014) made by this process.L-26

Figure 6: Form fixture hardening: (a) schematic of a lineK-23, (b) bumper beam of Ford Mustang (2004-2014) made by this process.L-26

 

Form fixture hardening parts have been used in low volume cars such as Porsche 911 or Bentley Mulsanne. In some cars, form fixture hardening was used to manufacture the A-pillar of the convertible (cabriolet) versions of high-volume cars, especially in Europe. Most of these applications involved uncoated boron alloyed tubes (similar to 22MnB5).H-28  The 5th generation Ford Mustang (2004-2014) had form fixture hardened bumper beams in the front and rear, as seen in Figure 6b.L-26  The form fixture hardening process allows for use of AlSi coatings, since the steel goes through a furnace rather than an induction hardening step. Special care must be taken in cold roll-forming process to ensure the AlSi coating is not damaged.K-23

 

Form Blow Hardening / Hot Gas Metal Forming

(Cut-to-length tube or roll formed and welded profile > Heating > Pressure forming > Quenching > Piercing)

In hot gas metal forming, the tube or roll formed closed profile is heated first and placed onto a die set. The ends of the tube are sealed and pressurized gas or granular medium is forced inside the tubular blank. The forming forces are applied by the high pressure built inside the tube.C-16  It is also possible to end-feed material as in the case of (cold) tube hydroforming. After the deformation, the part is quenched either with water (form blow hardening) or by the air inside and the surface of the tool cavity (hot gas metal forming). In the latter case, similar to direct process, a water-cooling channel system inside the die inserts are typically required.K-23

Fraunhofer IWU has developed a hot gas metal forming setup in which both forming and quenching are done by compressed air. As shown in Figure 7a, the internal pressure can be increased to 70 MPa (700 bars) in only 6 seconds. The tools are cooled with internal cooling channels, Figure 7b. The parts produced with this technique have hardness values between 460 and 530 HV. Crashbox and camshafts are among the parts produced.L-27, N-16

Figure 7: Blow forming and quenching with air: change of pressure in the tube and temperature of the tube, (b) simulation of heat transfer to the dies and cooling channels (recreated after Citation N-16)

Figure 7: Blow forming and quenching with air: (a) change of pressure in the tube and temperature of the tube, (b) simulation of heat transfer to the dies and cooling channels (recreated after Citation N-16)

 

In 2011, Spanish car maker SEAT published a study on form blow hardening process. In this study, they replaced the A-pillar and cantrail assembly of the SEAT León (Mk2, SOP 2005) with one form blow hardened part. The results were summarized asO-7:

  1. 7.9kg weight reduction per car,
  2. Sheet material utilization increased from 40 to 95%,
  3. Number of components in the assembly on one side of the car reduced from 5 to 2, and the roof rail was eliminated.

One advantage of this technology is the possibility to use the same die set for different wall thickness tubes. By doing so, parts can be produced for different variants of a car (i.e., coupe and cabrio, or North American spec. vs. emerging market spec.). This information applies to monolithic (i.e., same thickness throughout the tube) and tailor rolled/welded tubes as well.F-16  In 2017, tubular parts are hot gas formed by using 1900 MPa PHS tubes for customer trials.F-17

Since 2018, form blow hardening is being used in the Ford FocusB-16 and Jeep Wrangler.B-17 In the Ford Focus, a tailor rolled tube with thicknesses between 1.0 and 1.8 mm is used in Europe, whereas in China it is a monolithic (same thickness everywhere) 1.6 mm thick tube.F-16

 

3-Dimensional Hot Bending and Quenching (3DQ)

(Cut-to-length tube > Local induction heating > 3-D Bending > Direct Water Quenching > Piercing)

In the 3DQ process, a tubular profile with constant cross section is quickly heated by induction heaters. By using movable roller dies, the part is bent. As the material is fed, water is sprayed on the induction heated portion of the tube to quench and harden it. The schematic of the process and the material strength through the process is illustrated in Figure 8. It is also possible to replace the movable roller dies with an industrial robot to bend and twist the tubular part.T-25

Figure 8: Schematic of 3DQ system (re-created after Citation T-25)

Figure 8: Schematic of 3DQ system (re-created after Citation T-25)

 

In January 2013, Mazda announced that the ISOFIX connection in the rear seats of a Premacy MPV (known as Mazda 5 in some markets) model was produced by this method, as shown in Figure 9a.M-24  In 2016, Honda started production of the sports car NSX (known as Acura NSX in some markets). This vehicle’s A-pillars were produced by 3DQ process, as shown in Figure 9b.H-29

Figure 9: 3DQ applications: (a) Seat reinforcement of Mazda 5/PremacyM-24, (b) Acura NSX’s A-pillar.H-29

Figure 9: 3DQ applications: (a) Seat reinforcement of Mazda 5/PremacyM-24, (b) Acura NSX’s A-pillar.H-29

 

The technology has been used on uncoated blanks. In 2019, an academic study showed the feasibility of using Zn coated blanks in the 3DQ process.R-10

 

 

Steel Tube Air Forming process (STAF)

(Cut-to-length tube > Cold bending > Heating > Press Forming > Pressure Forming > Quenching > Piercing)

Steel Tube Air Forming process (STAF) is a modified and enhanced version of hot gas metal forming. In the STAF process, a metal tube is bent in a small press at room temperature. The preformed tube is transferred to the main press, where it is heated to the critical temperature using electrical conduction (Joule heating) by passing current through the tube. The first step creates the flanges where the press closes on the partially air blow formed tube. In the second step, air pressure completes the process by forming the desired cross section and overall shape.

As seen in Figure 10, the parts made with the STAF process can have a flange area for further welding/joining to other car body components. Some peripheral parts can be integrated into a single STAF part, improving productivity and manufacturing cost. The continuous closed cross section is created without the need for spot welding, improving stiffness and further reducing manufacturing costs. These factors combine to result in mass savings compared with conventional hot formed components, as indicated in Figure 11. F-18, F-41, F-42

Figure 10: The Steel Tube Air Forming process compared with other manufacturing approaches. STAF integrates flange formation without the need for additional spot welding.F-42  HSS stands for High-Strength Steel and may refer to conventional HSS or Advanced High-Strength Steels (AHSS).

Figure 10: The Steel Tube Air Forming process compared with other manufacturing approaches. STAF integrates flange formation without the need for additional spot welding.F-42  HSS stands for High-Strength Steel and may refer to conventional HSS or Advanced High-Strength Steels (AHSS).

 

Figure 11: The STAF process may reduce part count, assembled weight, and manufacturing complexity compared with other manufacturing approaches.F-41

Figure 11: The STAF process may reduce part count, assembled weight, and manufacturing complexity compared with other manufacturing approaches.F-41

 

 

The following video, kindly provided by Sumitomo Heavy Industries, highlights the STAF process along with associated benefits.F-41

 

 

eren billur, PhD Thanks are given to Eren Billur, Ph.D., Billur MetalForm, who contributed this article.

 

 

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Coatings for PHS

Coatings for PHS

 

Overview

The initial press hardening steels of the 1970s were delivered bare, without a galvanized or aluminized layer for corrosion protection (i.e., uncoated). During the heating process, an oxide layer of FeOx forms if the furnace atmosphere is not controlled. Through the years, several coating technologies have been developed to solve the following problems of uncoated steelsF-14, F-33:

  1. Scale formation, which causes abrasive wear and requires a secondary shotblasting process before welding,
  2. Decarburization, which leads to softening close to the surface,
  3. Risk of corrosion.

The first commercially available coating on press hardening steels was patented in 1998. The coating was designed to solve the scaling problem, but it also offered some corrosion resistance.C-24 Since the coating composition is primarily aluminium, with approximately 9% silicon, it is usually referred to as AlSi, Al-Si, or AS.

Coating thickness is nominally 25 μm (75 g/m2) on each side and referenced as AS150. A more recent offering is a thinner coating of 13 μm (AS80).A-51 The AS coating requires a special heating curve and soaking time for better weldability, corrosion resistance and running health of the furnace. Most OEMs now include furnace dew point limitations to reduce/avoid hydrogen embrittlement risk.

In 2005, Volkswagen was looking for a method to manufacture deep drawn transmission tunnels and other complex-to-form underbody components using press hardened steels. Although AS coatings were available, parts could not be formed to the full draw depth using the direct process, and AS coated blanks cracked during the cold forming portion of the two-step hybrid process. Using uncoated blanks led to severe scale formation, which increased the friction coefficient in hot forming. For this particular problem, a varnish coating was developed. The coating was applied at a steel mill, and shipped to Volkswagen’s stamping plant. The parts were first cold pre-formed and then heated in a furnace, as seen in Figure 1a. Hot pre-forms were then deep drawn to tunnels. As shown in Figure 1b, scale formed on parts which did not have the coating. A varnish coated blank could be cold formed without any scale, Figure 1c.S-63, F-34 Since then, some other varnish coatings also have been developed.

Figure 1: Transmission tunnel of 2005 Volkswagen Passat: (a) hot forming of pre-form, and final parts: (a) uncoated blank would suffer from scaling, (c) scale-free parts can be formed from varnish-coated blanks [REFERENCE 7]

Figure 1: Transmission tunnel of 2005 Volkswagen Passat: (a) hot forming of pre-form, and final parts: (a) uncoated blank would suffer from scaling, (c) scale-free parts can be formed from varnish-coated blanks.F-34

 

In car bodies, components that are sealed from external moisture are referred to as dry areas. These areas have low risk of corrosion. Areas that may be exposed to moisture are wet areas. Precautions must be taken to avoid corrosion of the sheet metal, such as using galvanized or pre-coated steel. Sealants can also be applied to joints to keep out moisture. The presence of humidity in these areas increases the risk of forming a galvanic cell, leading to accelerated corrosion. These areas have higher risk of corrosion and may require additional measures. Figure 2 shows dry and wet areas. In this figure, parts colored with yellow may be classified as wet or dry, depending on the vehicle design and the OEMs requirements.G-41

Figure 2: Dry and wet areas in a car body. [REFERENCE 8]

Figure 2: Dry and wet areas in a car body.G-41

 

An estimated ~40% of press hardened components are in dry areas. Thus, high corrosion protection is desired in the 60% of all press hardened components which are employed in wet areas.B-48  Zn-based coatings are favored for their cathodic protection, but require tight process control. The first commercial use of Zn-coated PHS was in 2008, using the indirect process.P-20 Since then, direct forming of Zn-coated PHS has been studied. When direct formed, furnace soaking temperature and time must be controlled carefully to avoid deep microcracks.G-41, K-20  Recently developed are two new Zn-coated press hardening steel grades, 20MnB8 and 22MnSiB9-5, both reaching approximately 1500 MPa tensile strength after processing. Using grades requires a pre-cooling process after the furnace to solidify the Zn-based coating. 20MnB8 can be direct hot formed to final shape, whereas 22MnSiB9-5 can be formed in a transfer press in the “multi-step” process.K-21, H-27

Depending on the coating type and thickness, the process type, controls and investment requirements may change significantly. For example, some press hardening lines may be designed to form blanks with only Al-based coatings. Table 1 summarizes the advantages and disadvantages of several coating systems.

Table 1: Summary of coatings available for press hardening steels.

Table 1: Summary of coatings available for press hardening steels.

Uncoated Blanks

The earliest press hardening steels did not have any coating on them. These steels are still available and may be preferred for dry areas in automotive applications. If the steel is uncoated and the furnace atmosphere is not controlled, scale formation is unavoidable. Scale is the term for iron oxides which form due to high temperature oxidation. Scale thickness increases as the time in furnace gets longer, as seen in Figure 3. Scale has to be removed before welding, requiring a shotblasting stage. Thicker scale is more difficult and more costly to remove.M-53 Early attempts to reduce (if not avoid) scale formation saw the use of an inert-gas atmosphere inside the furnace.A-52  Today, a mixture of nitrogen (N2) and natural gas (CH4) is typically used.F-35 In China, at least one tier supplier is using a vacuum furnace to prevent scale formation.A-68

Figure 3: Oxide layer (scale) on press hardened steel after: (a) fast resistance heating (10 seconds in air), (b) furnace heating (120 seconds in air) [REFERENCE 14]

Figure 3: Oxide layer (scale) on press hardened steel after: (a) fast resistance heating (10 seconds in air), (b) furnace heating (120 seconds in air).M-53

 

While heating uncoated steel in the furnace, if the conditions are favorable for iron (Fe) oxidation, carbon (C) may also be oxidized. When the carbon is oxidized, layers close to the surface lose their carbon content as gaseous carbon monoxide (CO) and/or carbon dioxide (CO2) is produced.S-87 The depth of the “decarburization layer” increases with dwell time in the furnace, until an oxide layer (scale) formed. Scale acts as a barrier between the bare steel and atmosphere. As the carbon is depleted in the “decarburization layer”, the hardness of the layer is decreased, as seen in Figure 4. Decarburization is usually undesirable since it lowers the strength/hardness and may negatively affect fatigue life.C-26

Figure 4: Hardness distribution of an uncoated steel after 6 minutes in a 900 °C furnace, showing hardness decrease as the surface layers lose their carbon. Image recreated after REFERENCE 19.

Figure 4: Hardness distribution of an uncoated steel after 6 minutes in a 900 °C furnace, showing hardness decrease as the surface layers lose their carbon. Image recreated after C-26.

 

Several methods are available to improve the corrosion resistance of uncoated PHS parts:

  1. E-coating after welding, before painting is a typical step of car body manufacturing, for rustproofing.
  2. If descaling can be done by using chromium shots (in shotblasting), a thin film of chromium-iron may grow on the surface and improve the corrosion resistance.F-14
  3. Vapor galvanizing (also known as Sherardizing) of uncoated steel after descaling, an experimental study described in Citation G-42.
  4. Electro-galvanizing after hot stamping, as described in Citation A-68.
  5. Change the base metal chemistry to one that is more oxidation resistant.L-60  Figure 5 compares the shiny non-oxidized surface appearance of parts made from this grade with that made from a conventional uncoated press hardening grade on the same production line with the same processing conditions.W-28

 

Figure 5: Oxidation resistant PHS grades may not need descaling or coatings for sufficient corrosion resistance. Citation W-28

Figure 5: Oxidation resistant PHS grades may not need descaling or coatings for sufficient corrosion resistance.W-28

 

Aluminium-Based Coatings

The first commercially available coating on press hardening steels was patented by Sollac (now part of ArcelorMittal) in 1998. This coating was designed to address the scaling problem, but also offers some barrier corrosion resistance.C-24  The nominal coating composition is 9-10 wt.% Si, 2-4 wt.% Fe, with the balance Al.L-39 The coating may be referred to as AlSi, Al-Si, AluSi or more commonly AS. Nominal as-delivered coating thickness is 25 μm (approximately 75 g/m2) on each side, and is usually referred to as AS150, with 150 referencing the total coating weight combining both sides, expressed as g/m2. More recently, a thinner coating of 13 μm (30-40 g/m2 on each side, AS60 or AS80) is now commercially available.A-51 When AS coated blanks are “tailor rolled,” the coating thickness is also reduced in a similar percentage of the base metal thickness reduction. Corrosion protection is similarly reduced, and furnace parameters need to be adjusted accordingly.

As delivered, AS150 has a coating thickness of 20-33 μm and a hardness of approximately 60 HV. The “interdiffusion layer” (abbreviated as IDL) has a high hardness and low toughness at delivery, as seen in Figure 6a. Due to the brittle nature of the IDL, AS coated blanks cannot be cold formed unless very special precautions are taken. During heating, iron from the base metal diffuses to the coating forming very hard AlSiFe (or AlFe) layers close to surface. At the same time, Al and Si of the coating diffuse to the IDL, growing it in thickness and reducing its hardness, Figure 6b. Earlier studies have shown that heating time (and also furnace temperature) has direct effect on the final thickness of IDL, as shown in Figure 7. Once the IDL thickness surpasses approximately 16 to 17 μm, the welding current range (ΔI = Iexpulsion – Imin) may be well below 2 kA.V-15, V-21, W-34  The dwell time must be long enough to ensure proper surface roughness (see Figure 6b) for e-coatability.M-27, T-40  Figure 10 summarizes the heating process window of AS coatings. The process window may change with base metal and coating thicknesses.

Figure 5: AS coating micrographs: (a) as-delivered, (b) after hot stamping process (re-created after REFERENCES 21, REFERENCE 22, REFERENCE 23, REFERENCE 26)

Figure 6: AS coating micrographs: (a) as-delivered, (b) after hot stamping process (re-created after V-15, V-21, W-34, G-32)

 

Figure 6: IDL thickness variation with furnace dwell time (Image created by REFERENCE 43 using raw data from REFERENCE 22, REFERENCE 26, and REFERENCE 27]

Figure 7: IDL thickness variation with furnace dwell time (Image created by B-55 using raw data from V-21, G-32, K-41.)

 

Hydrogen induced cracking (HIC, also known as hydrogen embrittlement) has been a major problem for steels over 1500 MPa tensile strength. AS coated steels may have higher diffusible hydrogen, when delivered, due to the aluminizing process occurring at 680 °C. In addition, AS coated grades may have a hydrogen absorption rate up to three times higher during heating.C-27  To reduce the hydrogen diffusion, it is essential to control the heating process (both heating rate and dew point in the furnace). AS coated blanks absorb hydrogen at room temperature; however, this happens at much lower rates than uncoated or Zn-coated blanks.J-21  Diffusible hydrogen can be removed from the press hardened part by re-heating the part to around 200 °C for 20 minutes or longer, in a process called de-embrittlement.V-21, G-32, G-43, J-21

For the abovementioned reasons, AS coated higher strength grades (i.e., PHS1800 and over) are required to have precise “dew point regulations” during the heating in furnace. Their final properties, especially elongation and bending angle, may be guaranteed only after bake hardening, as shown in Figure 8.B-32  Paint baking is standardized in Europe as a treatment for 20 minutes at 170 °C, which may act like a de-embrittlement treatment.E-10  Some OEMs also require dew point control and “subsequent de-embrittlement treatment” for AS coated PHS1500.

Figure 7: Effect of diffusible hydrogen (Hdiff) on mechanical properties of: (a) uncoated PHS2000, (b) AS coated PHS2000 in an uncontrolled furnace atmosphere (REFERENCE 43 using raw data from REFERENCE 28)

Figure 8: Effect of diffusible hydrogen (Hdiff) on mechanical properties of: (a) uncoated PHS2000, (b) AS coated PHS2000 in an uncontrolled furnace atmosphere (B-55 using raw data from C-27).

 

Another method to reduce the risk of hydrogen embrittlement is to adjust the coating composition. The bath chemistry for a standard AlSi coating consists of up to 90% aluminum, about 8% to 11% silicon and a maximum of 4% iron. Adding a maximum of 0.5% alkaline earth metals, like magnesium, for example has been shown to result in 40% less hydrogen diffusion into steel.R-29, T-45

Although not common in the industry, Al-Zn and Zn-Al-Mg based coatings have also been developed for press hardening processes.F-14 Recently introduced is an aluminium-silicon coating with magnesium additions. When oxidized with water vapor, Mg releases less H2 and thus may reduce the diffusible hydrogen.S-88

AS coatings may cause costly maintenance issues in roller hearth furnaces, as the coating may contaminate the rollers.B-14 Special care has to be taken to avoid the issue or prolong the maintenance intervals.

 

Zinc-Based Coatings

AS coatings provide some corrosion protection, known as “barrier protection”, as the coating forms a barrier between the oxidizing environment and the bare steel. It is quite common in Europe for a car to have 12 years corrosion protection warranty. To achieve such corrosion resistance, a typical car may have over 85% of its components galvanized.S-89

The use of Zn-coated PHS has been relatively low, compared to AS coated and uncoated grades. In 2015, 76% of the PHS sold in EU27+Turkey was AlSi coated. In these markets, 18% of the PHS sold was uncoated and only 6% was Zn coated.D-20 This can be attributed to the susceptibility of Zn-coated PHS to Liquid Metal Embrittlement (LME, also known as Liquid Metal Assisted Cracks (LMAC) and Liquid Metal Induced Embrittlement (LMIE)).C-28, L-46

After heating and soaking in the furnace, the base metal should be in the austenitic phase. During heating, the Zn coating reacts with the base metal and forms a thin solid layer of body-centered-cubic solid solution of Zn in α-Fe, shown as α-Fe(Zn) in Figure 9. During deformation, a microcrack can be initiated in this layer at the grain boundaries of the austenite in the base metal, as indicated in Figure 9a. As the crack propagates, zinc from the α-Fe(Zn) layer diffuses along the austenite grain boundary and combines with iron from the base steel to form additional α-Fe(Zn), Figure 9b. Cracks propagate through the weak a-Fe(Zn) grain boundary layer, allowing liquid zinc (with diffused iron) to advance into the capillary crack (Figure 9c). After quenching, the base metal transforms to martensite and the liquid Zn transforms to a hard and brittle intermetallic phase, Γ-Fe3Zn10.C-28

Figure 8: Schematic illustration of microcrack formation. (re-created based on REFERENCE 37.)

Figure 9: Schematic illustration of microcrack formation. (re-created based on C-28.)

 

To avoid LME, three methods can be employedK-20:

  1. Forming in the absence of liquid Zn,
  2. Reducing stress level,
  3. Reducing material susceptibility.

There are no breakthroughs to address the last two items. Forming a part in the absence of liquid Zn involves either of two process routes: (1) Indirect press hardening (also known as form hardening), or (2) Pre-cooled direct processes.

In the direct forming of Zn-coated blanks, with or without pre-cooling, microcracks in the base metal may be observed. Microcracks less than 10 μm into the base metal does not affect the fatigue strength of the part.K-20 Microcrack depth is a function of coating thickness, furnace conditions (temperature and dwell time, see Figure 10), forming severity and forming temperature. It may be possible to direct form galvannealed (GA coated) blanks.

The boiling point of pure zinc (907 °C) is very close to the austenitization temperature of 22MnB5 (885 °C), so the heating process window of Zn-coated blanks must be controlled precisely. When the furnace dwell time is too short, deeper microcracks may be observed. When the furnace dwell time is too long, corrosion performance may be degraded. Thus, heating process window of Zn-coated blanks is significantly narrower than that of AS-coated blanks.B-14, S-90

Figure 9: Heating process window of AS and Zn coatings (representative data, may not be accurate for all sheet and coating thicknesses, re-created based on REFERENCE 34 and REFERENCE 39).

Figure 10: Heating process window of AS and Zn coatings (representative data, may not be accurate for all sheet and coating thicknesses, re-created based on B-14, S-90.

 

Zn-based coatings may result in very low diffusible hydrogen after press hardening. In one studyJ-21, no diffusible hydrogen was detected, as long as the furnace dwell times are shorter than 6 minutes. Even after 50 minutes in the furnace, diffusible hydrogen was found to be around 0.06 ppm. Zn coatings do not act as a barrier for hydrogen desorption (losing H through the surface). Even at room temperature, Zn coated blanks may lose most of the diffusible hydrogen within a few days (also referred to as aging).

Figure 10: Evolution of galvanized coating: (a) as delivered: Ferrite+Pearlite in base metal, almost pure Zn coating with Al-rich inhibition layer, (b) at high temperatures: austenite in base metal + α-Fe(Zn) and liquid Zn + surface oxides, (c) after press hardening: martensite in base metal + α-Fe(Zn) and Γ-phase coatings + surface oxides. The oxides are removed prior to welding and painting [REFERENCE 30]

Figure 11: Evolution of galvanized coating: (a) as delivered: Ferrite+Pearlite in base metal, almost pure Zn coating with Al-rich inhibition layer, (b) at high temperatures: austenite in base metal + α-Fe(Zn) and liquid Zn + surface oxides, (c) after press hardening: martensite in base metal + α-Fe(Zn) and Γ-phase coatings + surface oxides. The oxides are removed prior to welding and painting.J-21

 

Zn-based coatings may have a yellowish color after hot stamping. The surface oxides have to be removed before welding. This is typically done by shotblasting.

PHS blanks with a ZnNi coating were previously available. The ZnNi coating provided a low friction coefficient, a large process window in the furnace, the ability to be cold formed (indirect or two-step hybrid processes were also possible) and decreased susceptibility to LME.B-56  ZnNi coated PHS was used in the rear rail of the Opel Adam city carH-57 for a short period, until the coating was discontinued.C-29

 

Varnish Coatings

Another method to avoid scaling and decarburization is to apply varnish coatings. In this method, uncoated steel can be either coil coated or blanks can be manually coated with the paint-like varnish coatings.B-14  These coatings may also be known as “paint-type” or “sol-gel”.

Figure 11: Manual application of a varnish coating. [REFERENCE 7]

Figure 12: Manual application of a varnish coating.F-34

Depending on the type of coating, they may allow very fast heating – including induction and conduction heating with electric current. Since the coating does not require time to diffuse, furnace heating may be completed in less than 2 minutes.F-34 Again, depending on the type, surface conditioning may not be required before welding or e-coating.B-14

They were used in automotive industry between 2005 and 2010. By 2015 there were four different types of varnish coatings, some of which are now discontinued.B-14  These coatings may be useful for prototyping and low volume production.

 

eren billur, PhD Thanks are given to Eren Billur, Ph.D., Billur MetalForm, who contributed this article.

 

 

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